Synthesis, crystal structure, and catalytic epoxidation of a new oxovanadium(V) complex with benzohydrazone and benzohydroxamate mixed-ligands

Synthesis, crystal structure, and catalytic epoxidation of a new oxovanadium(V) complex with... Synthesis, characterization, and catalytic properties for styrene epoxidation of a new oxovanadium(V) complex [VOLL′] · CH3OH (I) derived from N′-(3-bromo-5-chloro-2-hydroxybenzylidene)-2-hydroxybenzohydrazide (H2L) and benzohydroxamic acid (HL′) are reported. Complex I was characterized by elemental analyses, IR, UV-Vis spectra and molar conductivity. Single crystal X-ray structure of complex I has been determined (CIF file CCDC no. 1034615). The V atom in the structure is in an octahedral coordination. In the crystal structure, molecules are linked through intermolecular O-H⋯O, O-H⋯Br and N-H⋯O hydrogen bonds, to form 2D layers. Catalytic property for epoxidation of styrene by the complex using PhIO and NaOCl as oxidant has been studied. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Synthesis, crystal structure, and catalytic epoxidation of a new oxovanadium(V) complex with benzohydrazone and benzohydroxamate mixed-ligands

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Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328415110093
Publisher site
See Article on Publisher Site

Abstract

Synthesis, characterization, and catalytic properties for styrene epoxidation of a new oxovanadium(V) complex [VOLL′] · CH3OH (I) derived from N′-(3-bromo-5-chloro-2-hydroxybenzylidene)-2-hydroxybenzohydrazide (H2L) and benzohydroxamic acid (HL′) are reported. Complex I was characterized by elemental analyses, IR, UV-Vis spectra and molar conductivity. Single crystal X-ray structure of complex I has been determined (CIF file CCDC no. 1034615). The V atom in the structure is in an octahedral coordination. In the crystal structure, molecules are linked through intermolecular O-H⋯O, O-H⋯Br and N-H⋯O hydrogen bonds, to form 2D layers. Catalytic property for epoxidation of styrene by the complex using PhIO and NaOCl as oxidant has been studied.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Nov 22, 2015

References

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