Synthesis, crystal structure, and catalytic epoxidation of a new oxovanadium(V) complex with benzohydrazone and benzohydroxamate mixed-ligands

Synthesis, crystal structure, and catalytic epoxidation of a new oxovanadium(V) complex with... Synthesis, characterization, and catalytic properties for styrene epoxidation of a new oxovanadium(V) complex [VOLL′] · CH3OH (I) derived from N′-(3-bromo-5-chloro-2-hydroxybenzylidene)-2-hydroxybenzohydrazide (H2L) and benzohydroxamic acid (HL′) are reported. Complex I was characterized by elemental analyses, IR, UV-Vis spectra and molar conductivity. Single crystal X-ray structure of complex I has been determined (CIF file CCDC no. 1034615). The V atom in the structure is in an octahedral coordination. In the crystal structure, molecules are linked through intermolecular O-H⋯O, O-H⋯Br and N-H⋯O hydrogen bonds, to form 2D layers. Catalytic property for epoxidation of styrene by the complex using PhIO and NaOCl as oxidant has been studied. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Synthesis, crystal structure, and catalytic epoxidation of a new oxovanadium(V) complex with benzohydrazone and benzohydroxamate mixed-ligands

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Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328415110093
Publisher site
See Article on Publisher Site

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