A new Mg(II) complex, [Mg(H2O)5(DMF)]·(L) (L = 1,5-naphthalenedisulfonate), has been obtained by reaction of MgCl2·6H2O with sodium 1,5-naphthalenedisulfonate in 3:1 (v/v) CH3CH2OH–H2O containing a small amount of DMF. The complex was characterized by elemental analysis, IR spectroscopic analysis, and X-ray single-crystal diffraction analysis. The results showed that the local geometry around the central Mg(II) ion is a distorted octahedral environment comprising five water molecules and one DMF molecule. The two-dimensional layered structure of complex is formed by intramolecular and intermolecular hydrogen bonding and π–π stacking. The complex has substantial antibacterial activity against Escherichia coli, Bacillus subtilis, and Staphylococcus albus.
Research on Chemical Intermediates – Springer Journals
Published: Oct 31, 2013
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