Synthesis, crystal structure, and antibacterial activity of a manganese(III) complex derived from N,N′-3,4-chlorophenylene-bis(5-methylsalicylaldimine)

Synthesis, crystal structure, and antibacterial activity of a manganese(III) complex derived from... A new mononuclear manganese(III) complex has been synthesized from the Schiff base compound N,N′-3,4-chlorophenylene-bis(5-methylsalicylaldimine) and manganese perchlorate in the presence of sodium azide. The complex has been characterized by physico-chemical and spectroscopic methods, as well as single crystal X-ray determination (CIF file CCDC no. 1054335). The Mn atom in the complex is six-coordinate by two nitrogen and two oxygen atoms of the Schiff base ligand, one nitrogen atom of an azide ligand, and one oxygen atom of a methanol ligand. Crystal structure of the complex is stabilized by hydrogen bonds and π···π interactions. The complex and the Schiff base compound were assayed for antibacterial activities against three Gram-positive bacterial strains (B. subtilis, S. aureus, and St. faecalis) and three Gram-negative bacterial strains (E. coli, P. aeruginosa, and E. cloacae) by MTT method. As a result, the complex showed effective antimicrobial activity against the microorganisms tested. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Synthesis, crystal structure, and antibacterial activity of a manganese(III) complex derived from N,N′-3,4-chlorophenylene-bis(5-methylsalicylaldimine)

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Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S107032841511010X
Publisher site
See Article on Publisher Site

Abstract

A new mononuclear manganese(III) complex has been synthesized from the Schiff base compound N,N′-3,4-chlorophenylene-bis(5-methylsalicylaldimine) and manganese perchlorate in the presence of sodium azide. The complex has been characterized by physico-chemical and spectroscopic methods, as well as single crystal X-ray determination (CIF file CCDC no. 1054335). The Mn atom in the complex is six-coordinate by two nitrogen and two oxygen atoms of the Schiff base ligand, one nitrogen atom of an azide ligand, and one oxygen atom of a methanol ligand. Crystal structure of the complex is stabilized by hydrogen bonds and π···π interactions. The complex and the Schiff base compound were assayed for antibacterial activities against three Gram-positive bacterial strains (B. subtilis, S. aureus, and St. faecalis) and three Gram-negative bacterial strains (E. coli, P. aeruginosa, and E. cloacae) by MTT method. As a result, the complex showed effective antimicrobial activity against the microorganisms tested.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Nov 3, 2015

References

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