Synthesis, characterization and using a new terpyridine moiety-based ion-imprinted polymer nanoparticle: sub-nanomolar detection of Pb(II) in biological and water samples

Synthesis, characterization and using a new terpyridine moiety-based ion-imprinted polymer... A highly selective lead-imprinted polymer was synthesized via a thermal precipitation polymerization technique based on a terpyridine-based ligand as the complexing agent. The synthesized polymer was successfully incorporated in a graphite paste electrode (GPE) as the recognition element for lead ion (Pb2+). Differential pulse anodic stripping voltammetry (DPASV) technique was used to transduce the binding events at the modified electrode. The imprinted polymer nanoparticles (IP-NPs) were synthesized by precipitation polymerization of ethylene glycol dimethacrylate as the cross-linker, 2,2′-azobisisobutyronitrile as the free radical initiator and 2,2′:6′,6″-terpyridine (terpy) as the recognition element. The sensing procedure is based on the accumulation of lead ions at − 1.0 V vs. Ag/AgCl. Afterward, the DPV was recorded by the sweeping potential in a positive direction to oxidize the accumulated ions, leading to the appearance of a significant anodic peak. The constructed IIP–GPE revealed a linear response toward Pb2+ over the concentration range from 0.4 to 10 nM (with the sensitivity of 693.95 nA nM−1 cm−2) and 10 nM to 1.0 µM (with the sensitivity of 580.25 µA µM−1 cm−2). The limit of detection (LOD) was evaluated to be 0.11 nM (for S/N = 3). The accuracy of the sensor was explored by analysis of a quality control material (QCMs, Seronorm™ urine REF NO 1011645) and different water samples. Selectivity studies showed no particular interference for detection of Pb(II). http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Chemical Papers Springer Journals

Synthesis, characterization and using a new terpyridine moiety-based ion-imprinted polymer nanoparticle: sub-nanomolar detection of Pb(II) in biological and water samples

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Publisher
Springer Journals
Copyright
Copyright © 2018 by Institute of Chemistry, Slovak Academy of Sciences
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering; Biochemistry, general; Medicinal Chemistry; Materials Science, general; Biotechnology
ISSN
0366-6352
eISSN
1336-9075
D.O.I.
10.1007/s11696-018-0523-6
Publisher site
See Article on Publisher Site

Abstract

A highly selective lead-imprinted polymer was synthesized via a thermal precipitation polymerization technique based on a terpyridine-based ligand as the complexing agent. The synthesized polymer was successfully incorporated in a graphite paste electrode (GPE) as the recognition element for lead ion (Pb2+). Differential pulse anodic stripping voltammetry (DPASV) technique was used to transduce the binding events at the modified electrode. The imprinted polymer nanoparticles (IP-NPs) were synthesized by precipitation polymerization of ethylene glycol dimethacrylate as the cross-linker, 2,2′-azobisisobutyronitrile as the free radical initiator and 2,2′:6′,6″-terpyridine (terpy) as the recognition element. The sensing procedure is based on the accumulation of lead ions at − 1.0 V vs. Ag/AgCl. Afterward, the DPV was recorded by the sweeping potential in a positive direction to oxidize the accumulated ions, leading to the appearance of a significant anodic peak. The constructed IIP–GPE revealed a linear response toward Pb2+ over the concentration range from 0.4 to 10 nM (with the sensitivity of 693.95 nA nM−1 cm−2) and 10 nM to 1.0 µM (with the sensitivity of 580.25 µA µM−1 cm−2). The limit of detection (LOD) was evaluated to be 0.11 nM (for S/N = 3). The accuracy of the sensor was explored by analysis of a quality control material (QCMs, Seronorm™ urine REF NO 1011645) and different water samples. Selectivity studies showed no particular interference for detection of Pb(II).

Journal

Chemical Papers – Springer Journals

Published: Jun 1, 2018

References

  • Sensitive voltammetric determination of lead released from ceramic dishes by using of bismuth nanostructures anchored on biochar
    Agustini, D; Mangrich, AS; Bergamini, MF; Marcolino-Junior, LH
  • Preparation of nano-sized Pb2+ imprinted polymer and its application as the chemical interface of an electrochemical sensor for toxic lead determination in different real samples
    Alizadeh, T; Amjadi, S
  • Combination of molecularly imprinted polymers and carbon nanomaterials as a versatile biosensing tool in sample analysis: recent applications and challenges
    Ansari, S
  • Novel developments and trends of analytical methods for drug analysis in biological and environmental samples by molecularly imprinted polymers
    Ansari, S; Karimi, M
  • A highly selective voltammetric sensor for sub-nanomolar detection of lead ions using a carbon paste electrode impregnated with novel ion imprinted polymeric nanobeads
    Bahrami, A; Besharati-Seidani, A; Abbaspour, A; Shamsipur, M
  • Selective solid-phase extraction and trace monitoring of lead ions in food and water samples using new lead-imprinted polymer nanoparticles
    Behbahani, M; Hassanlou, PG; Amini, MM; Moazami, HR; Abandansari, HS; Bagheri, A; Zadeh, SH
  • Synthesis, characterization and application of novel lead imprinted polymer nanoparticles as a high selective electrochemical sensor for ultra-trace determination of lead ions in complex matrixes
    Bojdi, MK; Mashhadizadeh, MH; Behbahani, M; Farahani, A; Davarani, SSH; Bagheri, A
  • Recent advances on ion-imprinted polymers
    Branger, C; Meouche, W; Margaillan, A
  • Lead-selective fluorescent optode membrane based on 3, 3′, 5, 5′-tetramethyl-N-(9-anthrylmethyl) benzidine
    Chan, WH; Yang, RH; Mo, T; Wang, KM
  • Boron-doped diamond as the new electrode material for determination of heavy metals
    Chomisteková, Z; Sochr, J; Svítková, J; Švorc, Ľ
  • Improving limits of detection. Microdisc versus microcylinder electrodes
    Cinková, K; Clark, M; Sokolov, SV; Batchelor-McAuley, C; Švorc, Ľ; Compton, RG
  • Boron-doped diamond electrode as sensitive and selective green electroanalytical tool for heavy metals environmental monitoring: zinc detection in rubber industry waste
    Culková, E; Švorc, Ľ; Tomčík, P; Durdiak, J; Rievaj, M; Bustin, D; Brescher, R; Lokaj, J
  • Analysis of waste water by x-ray fluorescence spectrometry
    Eksperiandova, L; Blank, A; Makarovskaya, Y
  • Lead (II) potentiometric sensor based on 1, 4, 8, 11-tetrathiacyclotetradecane neutral carrier and lipophilic additives
    Elmosallamy, MA; Fathy, AM; Ghoneim, AK
  • High selective SiO2–Al2O3 mixed-oxide modified carbon paste electrode for anodic stripping voltammetric determination of Pb(II)
    Ghiaci, M; Rezaei, B; Kalbasi, R
  • Wide linear range nanomaterial/ionophore-based electrode used for determination of lead in environmental and biological samples with differential pulse voltammetry
    Gholivand, MB; Pashabadi, A; Mohammadi, M
  • Synthesis and characterization of ion imprinted polymeric nanoparticles for selective extraction and determination of mercury ions
    Hashemi, B; Shamsipur, M; Javadi, A; Rofouei, MK; Shockravi, A; Tajarrod, N; Mandumy, N
  • Synthesis of ion imprinted polymeric nanoparticles for selective pre-concentration and recognition of lithium ions
    Hashemi, B; Shamsipur, M; Seyedzadeh, Z
  • Voltammetric studies of lead at a 1-(2-pyridylazo)-2-naphthol modified screen-printed carbon electrode and its trace determination in water by stripping voltammetry
    Honeychurch, KC; Hart, JP; Cowell, DC
  • PAN-incorporated Nafion-modified spectroscopic graphite electrodes for voltammetric stripping determination of lead
    Hu, Z; Seliskar, CJ; Heineman, WR
  • Simultaneous determination of lead (II) and cadmium (II) at a diacetyldioxime modified carbon paste electrode by differential pulse stripping voltammetry
    Hu, C; Wu, K; Dai, X; Hu, S
  • Preparation of Pb(II) ion imprinted polymer and its application as the interface of an electrochemical sensor for trace lead determination
    Hu, S; Xiong, X; Huang, S; Lai, X
  • A label-free colorimetric detection of lead ions by controlling the ligand shells of gold nanoparticles
    Hung, Y-L; Hsiung, T-M; Chen, Y-Y; Huang, C-C
  • ICP-MS—a powerful tool for high-precision trace-element analysis in earth sciences: evidence from analysis of selected USGS reference samples
    Jenner, G; Longerich, H; Jackson, S; Fryer, B
  • Determination of lead with a copper-based electrochemical sensor
    Kang, W; Pei, X; Rusinek, CA; Bange, A; Haynes, EN; Heineman, WR; Papautsky, I
  • Estimate of heavy metal contamination in soils after a mining accident using reflectance spectroscopy
    Kemper, T; Sommer, S
  • A novel silica trap for lead determination by hydride generation atomic absorption spectrometry
    Korkmaz, DK; Ertaş, N; Ataman, OY
  • High-sensitivity determination of lead and cadmium based on the Nafion-graphene composite film
    Li, J; Guo, S; Zhai, Y; Wang, E
  • Electrochemical determination of trace lead (II) with enhanced sensitivity and selectivity by three-dimensional nanoporous gold leaf and self-assembled homocysteine monolayer
    Li, Y; Liu, J; Yu, F; Tang, H; Zhao, F; Ye, B-C; Chen, W; Lv, X
  • Advanced sensing performance towards simultaneous determination of quaternary mixture of antihypertensives using boron-doped diamond electrode
    Moraes, JT; Salamanca-Neto, CAR; Švorc, Ľ; Sartori, ER
  • Advances in the manufacture of MIP nanoparticles
    Poma, A; Turner, APF; Piletsky, SA
  • In situ synthesis and properties of reduced graphene oxide/Bi nanocomposites: as an electroactive material for analysis of heavy metals
    Sahoo, PK; Panigrahy, B; Sahoo, S; Satpati, AK; Li, D; Bahadur, D
  • Macromolecules containing bipyridine and terpyridine metal complexes: towards metallosupramolecular polymers
    Schubert, US; Eschbaumer, C
  • Imprinted dispersion polymers: a new class of easily accessible affinity stationary phases
    Sellergren, B
  • Electrochemical sensing of cadmium and lead ions at zeolite-modified electrodes: optimization and field measurements
    Senthilkumar, S; Saraswathi, R
  • Synthesis of a novel nanostructured ion-imprinted polymer for very fast and highly selective recognition of copper (II) ions in aqueous media
    Shamsipur, M; Besharati-Seidani, A
  • Synthesis and characterization of novel ion-imprinted polymeric nanoparticles for very fast and highly selective recognition of copper(II) ions
    Shamsipur, M; Besharati-Seidani, A; Fasihi, J; Sharghi, H
  • Determination of ultra traces of lead in water samples after combined solid-phase extraction–dispersive liquid–liquid microextraction by graphite furnace atomic absorption spectrometry
    Shamsipur, M; Fattahi, N; Sadeghi, M; Pirsaheb, M
  • Direct measurement of zinc in plasma by atomic absorption spectroscopy
    Smith, J; Butrimovitz, G; Purdy, W
  • Heavy metals determination using various in situ bismuth film modified carbon-based electrodes
    Sochr, J; Machková, M; Machyňák, Ľ; Čacho, F; Švorc, Ľ
  • Design of titanium nitride-and wolfram carbide-doped RGO/GC electrodes for determination of gallic acid
    Stanković, DM; Ognjanović, M; Martin, F; Švorc, Ľ; Mariano, JF; Antić, B
  • Molecularly imprinted polymers: present and future prospective
    Vasapollo, G; Sole, RD; Mergola, L; Lazzoi, MR; Scardino, A; Scorrano, S; Mele, G
  • Processes during anodic stripping voltammetry determination of lead in the presence of copper on a solid electrode modified with 2, 2′-bipyridyl in polyaniline
    Wagner, K; Strojek, J; Koziel, K
  • Thiacalixarene covalently functionalized multiwalled carbon nanotubes as chemically modified electrode material for detection of ultratrace Pb2+ ions
    Wang, L; Wang, X; Shi, G; Peng, C; Ding, Y
  • Guidelines for drinking-water quality
  • Simultaneous detection of Cd (II) and Pb(II) by differential pulse anodic stripping voltammetry at a nitrogen-doped microporous carbon/Nafion/bismuth-film electrode
    Xiao, L; Xu, H; Zhou, S; Song, T; Wang, H; Li, S; Gan, W; Yuan, Q
  • One-step synthesis of isoreticular metal–organic framework-8 derived hierarchical porous carbon and its application in differential pulse anodic stripping voltammetric determination of Pb(II)
    Xiao, L; Zhou, S; Hu, G; Xu, H; Wang, Y; Yuan, Q
  • Simultaneous determination of cadmium (II) and lead (II) with clay nanoparticles and anthraquinone complexly modified glassy carbon electrode
    Yuan, S; Chen, W; Hu, S
  • Determination of lead (II) by adsorptive stripping voltammetry using a glassy carbon electrode modified with β-cyclodextrin and chemically reduced graphene oxide composite
    Zhan, F; Gao, F; Wang, X; Xie, L; Gao, F; Wang, Q
  • Simultaneously determination of trace Cd 2+ and Pb 2+ based on l-cysteine/graphene modified glassy carbon electrode
    Zhou, W; Li, C; Sun, C; Yang, X

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