Synthesis, characterization, and non-isothermal curing kinetics of two silicon-containing arylacetylenic monomers

Synthesis, characterization, and non-isothermal curing kinetics of two silicon-containing... Vinyltri(phenylethynyl)silane ((ph–C≡C)3–Si–C=CH2; VTPES) and phenyltri(phenylethynyl)silane ((ph–C≡C)3–Si–ph; PTPES) were synthesized by Grignard reaction. Their molecular structures were characterized by means of 1H NMR, 13C NMR, 29Si NMR, and FT-IR spectroscopy. Their nonisothermal thermal curing processes were characterized by DSC, and the corresponding kinetic data, for example activation energy (E), pre-exponential factor (A), and the order of the reaction (n), were obtained by the Kissinger method. The results showed that the melting points of VTPES and PTPES were 84 and 116 °C, respectively. Their curing reaction rates were consistent with first-order kinetic equations. VTPES monomer had a lower activation energy and curing temperature as a result of coordination between reactive groups. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Synthesis, characterization, and non-isothermal curing kinetics of two silicon-containing arylacetylenic monomers

Loading next page...
 
/lp/springer_journal/synthesis-characterization-and-non-isothermal-curing-kinetics-of-two-yHymMBk0eR
Publisher
Springer Netherlands
Copyright
Copyright © 2011 by Springer Science+Business Media B.V.
Subject
Chemistry; Inorganic Chemistry; Catalysis; Physical Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-011-0291-1
Publisher site
See Article on Publisher Site

References

  • Fiber reinforced plastics using a new heat-resistant silicon based polymer
    Itoh, M; Inoue, K; Hirayama, N
  • Hydrosilylation of diynes as a route to functional polymers delocalized through silicon
    Sanchez, JC; Trogler, WC
  • Dehydrogenative cross-coupling reactions between phenylsilane and ethynylbenzene in the presence of metal hydrides
    Ishikawa, J; Inoue, K; Itoh, M

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 12 million articles from more than
10,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Unlimited reading

Read as many articles as you need. Full articles with original layout, charts and figures. Read online, from anywhere.

Stay up to date

Keep up with your field with Personalized Recommendations and Follow Journals to get automatic updates.

Organize your research

It’s easy to organize your research with our built-in tools.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

Monthly Plan

  • Read unlimited articles
  • Personalized recommendations
  • No expiration
  • Print 20 pages per month
  • 20% off on PDF purchases
  • Organize your research
  • Get updates on your journals and topic searches

$49/month

Start Free Trial

14-day Free Trial

Best Deal — 39% off

Annual Plan

  • All the features of the Professional Plan, but for 39% off!
  • Billed annually
  • No expiration
  • For the normal price of 10 articles elsewhere, you get one full year of unlimited access to articles.

$588

$360/year

billed annually
Start Free Trial

14-day Free Trial