Synthesis, characterization and adsorption behavior of cesium, cobalt, and europium on organic-inorganic hybrid exchanger

Synthesis, characterization and adsorption behavior of cesium, cobalt, and europium on... Polyacrylonitrile titanium tungstophosphate was prepared by mixing of polymer with the matrices of inorganic precipitate of titanium tungstophosphate to form composite cation-exchanger. Ion-exchange properties, thermal stability, distribution features and other performances were studied to understand the cation-exchange behavior of the obtained material. Physico-chemical properties of the material were determined using AAS, inductive coupled plasma spectrometry (ICPS), elemental analysis, IR, differential thermal and thermogravimetric analysis TGA-DTA, X-ray diffraction patterns (XRD), X-ray fluorescence spectrometry (XRF) and SEM studies. The material was found to be highly selective for Cs+ ion. The selectivity coefficients for different cations were determined, physical thermodynamic parameters such as the Gibbs free energy change ΔG*, entropy of activation ΔS*, and enthalpy (ΔH) were calculated. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Synthesis, characterization and adsorption behavior of cesium, cobalt, and europium on organic-inorganic hybrid exchanger

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Publisher
Springer Journals
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427215030234
Publisher site
See Article on Publisher Site

Abstract

Polyacrylonitrile titanium tungstophosphate was prepared by mixing of polymer with the matrices of inorganic precipitate of titanium tungstophosphate to form composite cation-exchanger. Ion-exchange properties, thermal stability, distribution features and other performances were studied to understand the cation-exchange behavior of the obtained material. Physico-chemical properties of the material were determined using AAS, inductive coupled plasma spectrometry (ICPS), elemental analysis, IR, differential thermal and thermogravimetric analysis TGA-DTA, X-ray diffraction patterns (XRD), X-ray fluorescence spectrometry (XRF) and SEM studies. The material was found to be highly selective for Cs+ ion. The selectivity coefficients for different cations were determined, physical thermodynamic parameters such as the Gibbs free energy change ΔG*, entropy of activation ΔS*, and enthalpy (ΔH) were calculated.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Jun 25, 2015

References

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