Continuous substitutional solid solutions between cobalt and nickel phosphates with varied degree of anion protonation were obtained: Co1−x Ni x HPO4·1.5H2O and (Co1−x Ni x )3(PO4)2·8H2O, where 0 ≤ x ≤ 1.00. The thermolysis of the solid solutions was studied by the example of Co1−x Ni x HPO4·1.5H2O. The phases synthesized were compared with the previously described continuous solid solution Co1−x Ni x (H2PO4)2·2H2O.
Russian Journal of Applied Chemistry – Springer Journals
Published: Jul 25, 2009
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