Synthesis and structure of mono- and polynuclear Cu(II) complexes with α-(N-benzoxazolin-2-one)acetic acid

Synthesis and structure of mono- and polynuclear Cu(II) complexes with... Two compounds with the α-(N-benzoxazolin-2-one)acetic acid ligand (L) were synthesized: [Cu(L)2(NH2C2H4OH)2] (I) and [Cu(L)2(H2O)2] n (II), viz., mono- and polynuclear complexes, respectively. According to X-ray diffraction data (CIF files CCDC no. 1008795 (I) and 1008794 (II)), the coordination polyhedron of the metal atom in I is an extended tetragonal bipyramid with four heteroatoms of two monoethanolamine molecules in the equatorial plane. The carboxyl oxygen atoms of two ligands L occupy the apical positions. In complex II, a tetragonal bipyramid is also formed, having two O atoms of the carboxyl groups of the L molecule and two water O atoms in the equatorial plane. Two oxygen atoms of the carboxyl groups of the L molecule occupy apical positions. Complex II is a 2D polymer (polymerization involves four O atoms of the carboxyl group) with the [CuL2(H2O)2] unit. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Synthesis and structure of mono- and polynuclear Cu(II) complexes with α-(N-benzoxazolin-2-one)acetic acid

Loading next page...
 
/lp/springer_journal/synthesis-and-structure-of-mono-and-polynuclear-cu-ii-complexes-with-n-lPGyixebwp
Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S107032841503001X
Publisher site
See Article on Publisher Site

Abstract

Two compounds with the α-(N-benzoxazolin-2-one)acetic acid ligand (L) were synthesized: [Cu(L)2(NH2C2H4OH)2] (I) and [Cu(L)2(H2O)2] n (II), viz., mono- and polynuclear complexes, respectively. According to X-ray diffraction data (CIF files CCDC no. 1008795 (I) and 1008794 (II)), the coordination polyhedron of the metal atom in I is an extended tetragonal bipyramid with four heteroatoms of two monoethanolamine molecules in the equatorial plane. The carboxyl oxygen atoms of two ligands L occupy the apical positions. In complex II, a tetragonal bipyramid is also formed, having two O atoms of the carboxyl groups of the L molecule and two water O atoms in the equatorial plane. Two oxygen atoms of the carboxyl groups of the L molecule occupy apical positions. Complex II is a 2D polymer (polymerization involves four O atoms of the carboxyl group) with the [CuL2(H2O)2] unit.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Mar 5, 2015

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 12 million articles from more than
10,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Unlimited reading

Read as many articles as you need. Full articles with original layout, charts and figures. Read online, from anywhere.

Stay up to date

Keep up with your field with Personalized Recommendations and Follow Journals to get automatic updates.

Organize your research

It’s easy to organize your research with our built-in tools.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve Freelancer

DeepDyve Pro

Price
FREE
$49/month

$360/year
Save searches from
Google Scholar,
PubMed
Create lists to
organize your research
Export lists, citations
Read DeepDyve articles
Abstract access only
Unlimited access to over
18 million full-text articles
Print
20 pages/month
PDF Discount
20% off