Synthesis and properties of epoxy derivatives of syndiotactic 1,2-polybutadiene

Synthesis and properties of epoxy derivatives of syndiotactic 1,2-polybutadiene Samples of modified 1,2-polybutadiene were prepared by the reaction of the polymer with peracetic acid or tert-butyl hydroperoxide in the presence of a catalyst, hexacarbonylmolybdenum. The hydrodynamic characteristics of dilute solutions and the rheological properties of concentrated solutions of the starting and epoxidized polydiene in hydrocarbon solvents were studied. The Huggins constant K x, second virial coefficient A 2, root-mean-square size of macromolecular coils $$(\overline {R^2 } )^{1/2} $$ , and the enthalpy, entropy, and Gibbs energy of activation of the viscous flow of solutions of the starting and modified polydiene were estimated. Russian Journal of Applied Chemistry Springer Journals

Synthesis and properties of epoxy derivatives of syndiotactic 1,2-polybutadiene

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Copyright © 2006 by Pleiades Publishing, Inc.
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
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