Synthesis and photophysical properties of new carbon-chain copolymers with europium-containing and carbazole fragments in pendant chains

Synthesis and photophysical properties of new carbon-chain copolymers with europium-containing... Functionalized polynorbornenes with terpyridine and carbazole groups in pendant chains were prepared by metathesis copolymerization. The polymeric products prepared react with europium thenoyltrifluoroacetonate to form new carbon-chain copolymers with different ratios of organic and europium-containing units. The polymeric materials prepared were characterized by IR and NMR spectroscopy, gel permeation chromatography, differential scanning calorimetry, and elemental analysis. All the europium-containing copolymers exhibit strong metal-centered photoluminescence in solution and in thin film. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Synthesis and photophysical properties of new carbon-chain copolymers with europium-containing and carbazole fragments in pendant chains

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Publisher
SP MAIK Nauka/Interperiodica
Copyright
Copyright © 2012 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427212120233
Publisher site
See Article on Publisher Site

Abstract

Functionalized polynorbornenes with terpyridine and carbazole groups in pendant chains were prepared by metathesis copolymerization. The polymeric products prepared react with europium thenoyltrifluoroacetonate to form new carbon-chain copolymers with different ratios of organic and europium-containing units. The polymeric materials prepared were characterized by IR and NMR spectroscopy, gel permeation chromatography, differential scanning calorimetry, and elemental analysis. All the europium-containing copolymers exhibit strong metal-centered photoluminescence in solution and in thin film.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Jan 23, 2013

References

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