Synthesis and optical properties of basic fuchsin dye-doped PMMA polymeric films for laser applications: wide scale absorption band

Synthesis and optical properties of basic fuchsin dye-doped PMMA polymeric films for laser... Basic fuchsin dye-doped poly(methyl methacrylate) polymeric films were sensitized with various dye concentrations ranging from 0.0833 to 1.667 wt% of basic fuchsin. Their structure, linear absorption, and optical limiting properties were examined. The films were prepared using a simple and fast casting technique dissolved in chloroform for both the dye and the polymer. Structural characterizations were achieved by XRD, and the films showed an amorphous hump supporting the noncrystalline structure of studied polymeric composites. Spectrophotometer measurements were used to estimate the spectral absorption measurements of the films such as transmittance, absorbance with the calculations of absorption index (k), and optical energy band gap (E g ) in the wavelength region from 190 to 2500 nm. Results show that the optical constants change with increasing the dye doping concentrations. It has been found that optical energy gap (E g ) appearing that, both direct and indirect optical transitions are conceivable for these films. Optical limiting properties of the films with various dye concentrations were studied using a continuous wave He–Ne laser operating at 632.8 nm. The results appeared that the sample has an obvious optical limiting effect. The designed BF/PMMA composites can be applicable in wide-scale applications. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Optical and Quantum Electronics Springer Journals

Synthesis and optical properties of basic fuchsin dye-doped PMMA polymeric films for laser applications: wide scale absorption band

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Publisher
Springer US
Copyright
Copyright © 2018 by Springer Science+Business Media, LLC, part of Springer Nature
Subject
Physics; Optics, Lasers, Photonics, Optical Devices; Electrical Engineering; Characterization and Evaluation of Materials; Computer Communication Networks
ISSN
0306-8919
eISSN
1572-817X
D.O.I.
10.1007/s11082-018-1425-0
Publisher site
See Article on Publisher Site

Abstract

Basic fuchsin dye-doped poly(methyl methacrylate) polymeric films were sensitized with various dye concentrations ranging from 0.0833 to 1.667 wt% of basic fuchsin. Their structure, linear absorption, and optical limiting properties were examined. The films were prepared using a simple and fast casting technique dissolved in chloroform for both the dye and the polymer. Structural characterizations were achieved by XRD, and the films showed an amorphous hump supporting the noncrystalline structure of studied polymeric composites. Spectrophotometer measurements were used to estimate the spectral absorption measurements of the films such as transmittance, absorbance with the calculations of absorption index (k), and optical energy band gap (E g ) in the wavelength region from 190 to 2500 nm. Results show that the optical constants change with increasing the dye doping concentrations. It has been found that optical energy gap (E g ) appearing that, both direct and indirect optical transitions are conceivable for these films. Optical limiting properties of the films with various dye concentrations were studied using a continuous wave He–Ne laser operating at 632.8 nm. The results appeared that the sample has an obvious optical limiting effect. The designed BF/PMMA composites can be applicable in wide-scale applications.

Journal

Optical and Quantum ElectronicsSpringer Journals

Published: Mar 12, 2018

References

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