Synthesis and molecular structure of a manganese tricarbonyl complex based on 5,6-nido-C2B8H12 carborane

Synthesis and molecular structure of a manganese tricarbonyl complex based on 5,6-nido-C2B8H12... The anionic manganese tricarbonyl complex [1,1,1-(CO)3-isonido-1,2,4-MnC2B8H10]–was synthesized in the form of PPN and tmdaH salts (PPN is bis(triphenylphosphine)iminium, tmda is N,N,N’,N’-tetramethyl-1,8-diaminonaphthalene) by the reaction of the deprotonated form of the medium-size non-icosahedral carborane 5,6-nido-C2B8H12 with Mn(CO)5Br. The structure of the complex [tmdaH][1,1,1-(CO)3-isonido-1,2,4-MnC2B8H10] was deter-mined by X-ray diffraction. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Chemical Bulletin Springer Journals

Synthesis and molecular structure of a manganese tricarbonyl complex based on 5,6-nido-C2B8H12 carborane

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Publisher
Springer US
Copyright
Copyright © 2017 by Springer Science+Business Media, LLC, part of Springer Nature
Subject
Chemistry; Chemistry/Food Science, general; Organic Chemistry; Inorganic Chemistry
ISSN
1066-5285
eISSN
1573-9171
D.O.I.
10.1007/s11172-017-1994-2
Publisher site
See Article on Publisher Site

Abstract

The anionic manganese tricarbonyl complex [1,1,1-(CO)3-isonido-1,2,4-MnC2B8H10]–was synthesized in the form of PPN and tmdaH salts (PPN is bis(triphenylphosphine)iminium, tmda is N,N,N’,N’-tetramethyl-1,8-diaminonaphthalene) by the reaction of the deprotonated form of the medium-size non-icosahedral carborane 5,6-nido-C2B8H12 with Mn(CO)5Br. The structure of the complex [tmdaH][1,1,1-(CO)3-isonido-1,2,4-MnC2B8H10] was deter-mined by X-ray diffraction.

Journal

Russian Chemical BulletinSpringer Journals

Published: Mar 14, 2018

References

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