Synthesis and Industrial Catalytic Applications of Binary and Ternary Molybdenum Nitrides: A Review

Synthesis and Industrial Catalytic Applications of Binary and Ternary Molybdenum Nitrides: A Review Keywords Molybdenum nitrides · Ammonia synthesis · Ammonia decomposition · Hydrodenitrogenation · Hydrodesulphurization 1 Introduction * Venkata Ramesh Babu Gurram Transition metal nitrides are the compounds in which gvrbchem@gmail.com nitrogen occupies interstitial position of the close packed * Seetha Rama Rao Kamaraju metallic structure. These are the compounds with wide ksramaraoiict@gmail.com range of properties like hardness, electrical or thermal CSIR-Academy of Scientific and Innovative Research (CSIR- conductivity, super conductivity, magnetism and catalytic AcSIR), New Delhi, India activity [1, 2]. Due to these properties several new nitride Catalysis Laboratory, Inorganic & Physical Chemistry materials are synthesized and used for the various appli- Division, CSIR-Indian Institute of Chemical Technology, cations. Synthesis of nitrides is very complex with large Hyderabad 500007, India Vol.:(0123456789) 1 3 V. R. B. Gurram et al. thermodynamic barriers which occur from making and Because of their chemical inertness and ability to with- −1 breaking of N≡N bonds (945 kJ mol ). The first industrial stand high temperatures, interstitial nitrides are useful in application of a nitride was the use of calcium cyanamide several high-temperature applications, including their use as a fertilizer. It is produced by the reaction of nitrogen as crucibles and high-temperature reaction vessels. TiN with calcium carbide. It gradually releases ammonia by [10–12], ZrN [13, 14], HfN [15], TaN http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Catalysis Surveys from Asia Springer Journals

Synthesis and Industrial Catalytic Applications of Binary and Ternary Molybdenum Nitrides: A Review

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Publisher
Springer US
Copyright
Copyright © 2018 by Springer Science+Business Media, LLC, part of Springer Nature
Subject
Chemistry; Catalysis; Physical Chemistry; Industrial Chemistry/Chemical Engineering; Characterization and Evaluation of Materials
ISSN
1571-1013
eISSN
1574-9266
D.O.I.
10.1007/s10563-018-9250-9
Publisher site
See Article on Publisher Site

Abstract

Keywords Molybdenum nitrides · Ammonia synthesis · Ammonia decomposition · Hydrodenitrogenation · Hydrodesulphurization 1 Introduction * Venkata Ramesh Babu Gurram Transition metal nitrides are the compounds in which gvrbchem@gmail.com nitrogen occupies interstitial position of the close packed * Seetha Rama Rao Kamaraju metallic structure. These are the compounds with wide ksramaraoiict@gmail.com range of properties like hardness, electrical or thermal CSIR-Academy of Scientific and Innovative Research (CSIR- conductivity, super conductivity, magnetism and catalytic AcSIR), New Delhi, India activity [1, 2]. Due to these properties several new nitride Catalysis Laboratory, Inorganic & Physical Chemistry materials are synthesized and used for the various appli- Division, CSIR-Indian Institute of Chemical Technology, cations. Synthesis of nitrides is very complex with large Hyderabad 500007, India Vol.:(0123456789) 1 3 V. R. B. Gurram et al. thermodynamic barriers which occur from making and Because of their chemical inertness and ability to with- −1 breaking of N≡N bonds (945 kJ mol ). The first industrial stand high temperatures, interstitial nitrides are useful in application of a nitride was the use of calcium cyanamide several high-temperature applications, including their use as a fertilizer. It is produced by the reaction of nitrogen as crucibles and high-temperature reaction vessels. TiN with calcium carbide. It gradually releases ammonia by [10–12], ZrN [13, 14], HfN [15], TaN

Journal

Catalysis Surveys from AsiaSpringer Journals

Published: Jun 6, 2018

References

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