Synthesis and fluorescence study of the grafted salicylidene Schiff base onto SBA-15 mesoporous silica for detecting Zn2+ traces in aqueous medium

Synthesis and fluorescence study of the grafted salicylidene Schiff base onto SBA-15 mesoporous... A selective fluorescent chemosensor was prepared by anchoring pyridine-2-carbaldehyde Schiff base ligand onto mesochannels of organically modified SBA-15 mesoporous silica. The resulting organic-inorganic hybrid mesoporous chemosensor was characterized by X-ray diffraction, Fourier transform IR spectroscopy, transmission electron microscopy, UV-visible diffuse reflectance spectra, and photoluminescence spectra. All the results support the idea that successive attachment of the ligand moiety onto one-pot-modified mesoporous scaffold has not altered its basic hexagonally arranged structure. Upon introducing trace amounts of zinc ions into aqueous solution, remarkable enhancement in the fluorescence was observed. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Synthesis and fluorescence study of the grafted salicylidene Schiff base onto SBA-15 mesoporous silica for detecting Zn2+ traces in aqueous medium

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Publisher
Springer Journals
Copyright
Copyright © 2016 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S10704272160030228
Publisher site
See Article on Publisher Site

Abstract

A selective fluorescent chemosensor was prepared by anchoring pyridine-2-carbaldehyde Schiff base ligand onto mesochannels of organically modified SBA-15 mesoporous silica. The resulting organic-inorganic hybrid mesoporous chemosensor was characterized by X-ray diffraction, Fourier transform IR spectroscopy, transmission electron microscopy, UV-visible diffuse reflectance spectra, and photoluminescence spectra. All the results support the idea that successive attachment of the ligand moiety onto one-pot-modified mesoporous scaffold has not altered its basic hexagonally arranged structure. Upon introducing trace amounts of zinc ions into aqueous solution, remarkable enhancement in the fluorescence was observed.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Jun 15, 2016

References

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