Synthesis and evaluation of a chiral menthol functionalized silsesquioxane: application to diastereoselective [2+2] photocycloaddition

Synthesis and evaluation of a chiral menthol functionalized silsesquioxane: application to... A novel chiral menthol derivative supported on silsesquioxane was easily synthesized by hydrosilylation of the corresponding arylmenthyl olefin with commercially available silsesquioxane-type hydrosilane. We evaluated the applicability of the silsesquioxane-based compound to diastereoselective [2+2] photocycloaddition reaction. The newly synthesized silsesquioxane-based chiral menthol derivative 9 indicated similar diastereoselectivity to the corresponding p-methoxyphenyl menthol derivative. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Synthesis and evaluation of a chiral menthol functionalized silsesquioxane: application to diastereoselective [2+2] photocycloaddition

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Publisher
Springer Netherlands
Copyright
Copyright © 2012 by Springer Science+Business Media B.V.
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-012-0635-5
Publisher site
See Article on Publisher Site

Abstract

A novel chiral menthol derivative supported on silsesquioxane was easily synthesized by hydrosilylation of the corresponding arylmenthyl olefin with commercially available silsesquioxane-type hydrosilane. We evaluated the applicability of the silsesquioxane-based compound to diastereoselective [2+2] photocycloaddition reaction. The newly synthesized silsesquioxane-based chiral menthol derivative 9 indicated similar diastereoselectivity to the corresponding p-methoxyphenyl menthol derivative.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Jun 16, 2012

References

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