Synthesis and crystal structure of tris[2-(N,N-dimethylthiocarbamoyl)benzimidazolato-1]cobalt(III)

Synthesis and crystal structure of tris[2-(N,N-dimethylthiocarbamoyl)benzimidazolato-1]cobalt(III) Conditions for the formation of a CoL3 complex, where L is the deprotonated benzimidazole-2-(N,N-dimethyl)carbothioamide molecule, are studied. The structure of the complex is determined by X-ray diffraction analysis. Each ligand in crystal of the complex is bonded to the metal atom by the bidentate chelate mode at the vertices of a distorted octahedron. The S and N atoms in the octahedron are in the cis-position to each other. All bonds with the same multiplicity in the ligands and in the CoS3N3 octahedron have almost the same length. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Synthesis and crystal structure of tris[2-(N,N-dimethylthiocarbamoyl)benzimidazolato-1]cobalt(III)

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Publisher
Nauka/Interperiodica
Copyright
Copyright © 2006 by Pleiades Publishing, Inc.
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328406040063
Publisher site
See Article on Publisher Site

Abstract

Conditions for the formation of a CoL3 complex, where L is the deprotonated benzimidazole-2-(N,N-dimethyl)carbothioamide molecule, are studied. The structure of the complex is determined by X-ray diffraction analysis. Each ligand in crystal of the complex is bonded to the metal atom by the bidentate chelate mode at the vertices of a distorted octahedron. The S and N atoms in the octahedron are in the cis-position to each other. All bonds with the same multiplicity in the ligands and in the CoS3N3 octahedron have almost the same length.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Apr 6, 2006

References

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