Synthesis and crystal structure of the new binuclear complex of cerium(III) nitrate with 4,4,10,10-tetramethyl-1,3,7,9-tetraazospiro[5.5]undecane-2,8-dione and the change in the periodical properties in isostructural series of lanthanide complexes with this ligand

Synthesis and crystal structure of the new binuclear complex of cerium(III) nitrate with... The centrosymmetrical binuclar complex of cerium(III) nitrate with bicyclic bis-urea 4,4,10,10-tetramethyl-1,3,7,9-tetraazospiro[5.5]undecane-2,8-dione or spirocarbone (Sk), [Ce(C11H20N4O2)(H2O)2(NO3)3]2 (I), is synthesized for the first time, and its structure is determined (CIF file CCDC 985758). The crystals of compound I are monoclinic: space group P21/n, a = 14.2797(13), b = 7.3922(6), c = 21.003(2) Å, β = 102.103(10)°, V = 2167.8(3) Å3, ρcalcd = 1.85 g/cm3, Z = 2. The cerium atom is coordinated by two oxygen atoms of two Sk molecules bound by the symmetry procedure (1 − x, −y, 1 − z), three bidentate nitrate anions, and two water molecules. The coordination polyhedron of the cerium atom is an irregular ten-vertex polyhedron. The Ce…Ce distance in the complex is 9.57 Å. The change in the periodical properties in a series of the Sk complexes with lanthanide(III) (Ce-Lu, except for Pm) nitrates is discussed. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Synthesis and crystal structure of the new binuclear complex of cerium(III) nitrate with 4,4,10,10-tetramethyl-1,3,7,9-tetraazospiro[5.5]undecane-2,8-dione and the change in the periodical properties in isostructural series of lanthanide complexes with this ligand

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Publisher
Springer Journals
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328415010066
Publisher site
See Article on Publisher Site

Abstract

The centrosymmetrical binuclar complex of cerium(III) nitrate with bicyclic bis-urea 4,4,10,10-tetramethyl-1,3,7,9-tetraazospiro[5.5]undecane-2,8-dione or spirocarbone (Sk), [Ce(C11H20N4O2)(H2O)2(NO3)3]2 (I), is synthesized for the first time, and its structure is determined (CIF file CCDC 985758). The crystals of compound I are monoclinic: space group P21/n, a = 14.2797(13), b = 7.3922(6), c = 21.003(2) Å, β = 102.103(10)°, V = 2167.8(3) Å3, ρcalcd = 1.85 g/cm3, Z = 2. The cerium atom is coordinated by two oxygen atoms of two Sk molecules bound by the symmetry procedure (1 − x, −y, 1 − z), three bidentate nitrate anions, and two water molecules. The coordination polyhedron of the cerium atom is an irregular ten-vertex polyhedron. The Ce…Ce distance in the complex is 9.57 Å. The change in the periodical properties in a series of the Sk complexes with lanthanide(III) (Ce-Lu, except for Pm) nitrates is discussed.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Jan 7, 2015

References

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