Synthesis and crystal structure of Ba2[(UO2)(C2O4)2(NCS)]NCS·7H2O

Synthesis and crystal structure of Ba2[(UO2)(C2O4)2(NCS)]NCS·7H2O Single crystals of Ba2[(UO2)(C2O4)2(NCS)]NCS · 7H2O were prepared and studied by X-ray diffraction. The crystals are monoclinic, space group P21/c, Z = 4, a = 13.508(5) Å, b = 12.268(4) Å, c = 14.965(5) Å, β = 115.38(1)°, V = 2240.6(13) Å3. The main structural units in the crystal are the island complex species [(UO2)(C2O4)2(NCS)]3− corresponding to the crystal chemical group AB 2 01 M1 (A = UO 2 2+ , B01 = C2O 4 2− , M1 = NCS−) of uranyl complexes, which are united into a three-dimensional framework through electrostatic interactions and through hydrogen bonds involving oxalate and isocyanate ions and water molecules. Russian Journal of Coordination Chemistry Springer Journals

Synthesis and crystal structure of Ba2[(UO2)(C2O4)2(NCS)]NCS·7H2O

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Copyright © 2006 by Pleiades Publishing, Inc.
Chemistry; Inorganic Chemistry; Physical Chemistry
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