Synthesis and crystal structure of {(2-α-pyridylethyl)tris(phenyl)phosphonium}trichlorozinc(II)

Synthesis and crystal structure of {(2-α-pyridylethyl)tris(phenyl)phosphonium}trichlorozinc(II) The structure of the complex {(2-α-pyridylethyl)tris(phenyl)phosphonium}trichlorozinc(II), which is an unexpected product of the reaction of the Zn2+ ion with coordinated 4,5-(2-pyridylethylene)dithio-1,3-dithiol-2-thione, is described. The reaction mechanism is studied by the ESI method of positive and negative ions. The crystals are monoclinic, space group P21/c, a= 16.129(3) Å, b = 11.167(2) Å, c = 14.874(3) Å β = 91.77(3)°, Z = 4. The Zn(II) atom has a quasi-tetrahedral environment of three chloride ions and one phosphonium cation coordinated at the nitrogen atom of the pyridyl fragment. Russian Journal of Coordination Chemistry Springer Journals

Synthesis and crystal structure of {(2-α-pyridylethyl)tris(phenyl)phosphonium}trichlorozinc(II)

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Copyright © 2006 by Pleiades Publishing, Inc.
Chemistry; Inorganic Chemistry; Physical Chemistry
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