Synthesis and characterization of 4-(alkylaminoisonitrosoacetyl)biphenyls and their complexes

Synthesis and characterization of 4-(alkylaminoisonitrosoacetyl)biphenyls and their complexes Three new substituted 4-(alkylaminoisonitrosoacetyl)biphenyls (ligands) derived from 4-biphenylhydroxymoyl chloride and corresponding amines were synthesized. The following aromatic and aliphatic amines were used for ligands: ethanolamine, 2-amino-4-methylphenol, and 2-(aminomethyl)pyridine. Mononuclear or binuclear cobalt(II), nickel(II), copper(II), zinc(II), cadmium(II), and lead(II) complexes with these ligands were synthesized. These compounds were characterized by elemental analyses, AAS, infrared spectra, and magnetic susceptibility measurements. The ligands were additionally characterized by 1H NMR. The results suggest that the ligands act as tridentate ligands. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Synthesis and characterization of 4-(alkylaminoisonitrosoacetyl)biphenyls and their complexes

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Publisher
Springer Journals
Copyright
Copyright © 2006 by Pleiades Publishing, Inc.
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328406020059
Publisher site
See Article on Publisher Site

Abstract

Three new substituted 4-(alkylaminoisonitrosoacetyl)biphenyls (ligands) derived from 4-biphenylhydroxymoyl chloride and corresponding amines were synthesized. The following aromatic and aliphatic amines were used for ligands: ethanolamine, 2-amino-4-methylphenol, and 2-(aminomethyl)pyridine. Mononuclear or binuclear cobalt(II), nickel(II), copper(II), zinc(II), cadmium(II), and lead(II) complexes with these ligands were synthesized. These compounds were characterized by elemental analyses, AAS, infrared spectra, and magnetic susceptibility measurements. The ligands were additionally characterized by 1H NMR. The results suggest that the ligands act as tridentate ligands.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Mar 4, 2006

References

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