Synthesis and catalytic activity of some divalent copper and manganese complexes of N-donor ligands

Synthesis and catalytic activity of some divalent copper and manganese complexes of N-donor ligands A series of copper(II) with 2-aminobenzonitrile and 3-(2-oxo-pyrrolidin-yl)-propionitrile were first synthesized and characterized, and the reaction of these nitriles with Cu(OAc) 2 ·H 2 O or CuCl 2 ·2H 2 O in ethanol resulted in the production of three novel copper complexes, I , II , and III . In addition, we obtained the manganese (II) oxygen complex ( IV ) in the process of synthesis of the manganese (II) nitrogen complex, in which o -phenylenediamine was used as the ligands to react with MnCl 2 ·4H 2 O. The structure of each complex was determined by X-ray diffraction analysis. Each complex was also characterized using elemental analysis, 1 H NMR and IR. The complexes were then all used to catalyze the Henry reaction, and moderate catalytic results were achieved. (Figure not available: see fulltext.) http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Synthesis and catalytic activity of some divalent copper and manganese complexes of N-donor ligands

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Publisher
Springer Netherlands
Copyright
Copyright © 2013 by Springer Science+Business Media Dordrecht
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-013-1136-x
Publisher site
See Article on Publisher Site

Abstract

A series of copper(II) with 2-aminobenzonitrile and 3-(2-oxo-pyrrolidin-yl)-propionitrile were first synthesized and characterized, and the reaction of these nitriles with Cu(OAc) 2 ·H 2 O or CuCl 2 ·2H 2 O in ethanol resulted in the production of three novel copper complexes, I , II , and III . In addition, we obtained the manganese (II) oxygen complex ( IV ) in the process of synthesis of the manganese (II) nitrogen complex, in which o -phenylenediamine was used as the ligands to react with MnCl 2 ·4H 2 O. The structure of each complex was determined by X-ray diffraction analysis. Each complex was also characterized using elemental analysis, 1 H NMR and IR. The complexes were then all used to catalyze the Henry reaction, and moderate catalytic results were achieved. (Figure not available: see fulltext.)

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Mar 17, 2013

References

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