Syntheses, luminescence, and hirshfeld surface analyses of three lanthanide coordination polymers directed by flexible carboxylate ligand

Syntheses, luminescence, and hirshfeld surface analyses of three lanthanide coordination polymers... Three new complexes, namely {[Ln(L)3(2,2'-Bipy)] n · 2H2O} (Ln = Pr (I), Sm (II) and Nd (III)) (HL = 3-(4-hydroxyphenyl)propanoic acid), have been synthesized and structurally characterized by single-crystal X-ray diffraction analyses (CIF files CCDC nos. 1045041 (I), 1045042 (II), 1045043 (III)). The structural determination revealed that I–III have similar dinuclear motifs, which can be further linked into 1D chain via the hydrogen bond interactions. Furthermore, the luminescent properties of I–III show the strong emissive power and feature. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Syntheses, luminescence, and hirshfeld surface analyses of three lanthanide coordination polymers directed by flexible carboxylate ligand

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Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S107032841510005X
Publisher site
See Article on Publisher Site

Abstract

Three new complexes, namely {[Ln(L)3(2,2'-Bipy)] n · 2H2O} (Ln = Pr (I), Sm (II) and Nd (III)) (HL = 3-(4-hydroxyphenyl)propanoic acid), have been synthesized and structurally characterized by single-crystal X-ray diffraction analyses (CIF files CCDC nos. 1045041 (I), 1045042 (II), 1045043 (III)). The structural determination revealed that I–III have similar dinuclear motifs, which can be further linked into 1D chain via the hydrogen bond interactions. Furthermore, the luminescent properties of I–III show the strong emissive power and feature.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Oct 11, 2015

References

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