Surface activity and thermodynamic data for pyridinium surfactants with an aminoacylmethyl group

Surface activity and thermodynamic data for pyridinium surfactants with an aminoacylmethyl group A series of cationic surfactants of the type 1-(alkylcarbamoylmethyl)pyridinium chloride (C n cmpCl, n = 12, 14, 16) was synthesized in high yield by use of a simple method. The chemical structures of C n cmpCl were confirmed by 1H NMR and 13C NMR spectroscopy and ESI–MS. The surface activity of C n cmpCl and thermodynamic data for micelle formation were investigated by measurement of surface tension and conductivity in pure water and in aqueous solutions of sodium chloride of different concentration at different temperature. The results showed a general decrease of CMC for C n cmpCl with the aminoacylmethyl group compared with traditional pyridinium surfactants. The effect of NaCl concentration on the surface activity of C n cmpCl was obvious. However, CMCs of C n cmpCl are not sensitive to temperature in pure water. Elevation of temperature does not favor micelle formation, and increasing the length of the hydrophobic chain is beneficial to micelle formation. Moreover, micelle formation is a thermodynamically favorable process, and the micellization process is entropy-driven. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Surface activity and thermodynamic data for pyridinium surfactants with an aminoacylmethyl group

Loading next page...
 
/lp/springer_journal/surface-activity-and-thermodynamic-data-for-pyridinium-surfactants-a7GCX995r3
Publisher
Springer Netherlands
Copyright
Copyright © 2013 by Springer Science+Business Media Dordrecht
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-013-1492-6
Publisher site
See Article on Publisher Site

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 12 million articles from more than
10,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Unlimited reading

Read as many articles as you need. Full articles with original layout, charts and figures. Read online, from anywhere.

Stay up to date

Keep up with your field with Personalized Recommendations and Follow Journals to get automatic updates.

Organize your research

It’s easy to organize your research with our built-in tools.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

Monthly Plan

  • Read unlimited articles
  • Personalized recommendations
  • No expiration
  • Print 20 pages per month
  • 20% off on PDF purchases
  • Organize your research
  • Get updates on your journals and topic searches

$49/month

Start Free Trial

14-day Free Trial

Best Deal — 39% off

Annual Plan

  • All the features of the Professional Plan, but for 39% off!
  • Billed annually
  • No expiration
  • For the normal price of 10 articles elsewhere, you get one full year of unlimited access to articles.

$588

$360/year

billed annually
Start Free Trial

14-day Free Trial