Access the full text.
Sign up today, get DeepDyve free for 14 days.
Loading next page...
/lp/springer_journal/supramolecular-ensemble-of-a-coordination-compound-of-cdi2-with-2-YedihRyoQD
References (9)
-
Y. Kokunov, Yu. Gorbunova, V. Kovalev, S. Kozyukhin (2013)
Silver complexes with 2-amino-4-methylpyrimidine: Synthesis, crystal structure, and luminescent propertiesRussian Journal of Coordination Chemistry, 39
-
Y. Kokunov, Yu. Gorbunova, V. Kovalev (2012)
Synthesis and structure of silver coordination polymer with extended ditopic ligand containing terminal amino groups [Ag(C24H28N2)1.5]NO3Russian Journal of Inorganic Chemistry, 57
-
Y. Kokunov, Yu. Gorbunova, V. Kovalev, S. Kozyukhin (2013)
Coordination compounds of cobalt(II) and cadmium(II) with 2-amino-4-methylpyrimidine: Synthesis, crystal structure, and luminescent propertiesRussian Journal of Inorganic Chemistry, 58
-
Jong-Ho Lee, B. Lewis, J. Mendes, M. Turnbull, F. Awwadi (2003)
Transition metal halide salts and complexes of 2-aminopyrimidine: manganese(II) compounds – crystal structures of (2-aminopyrimidinium)4 [MnCl4(H2O)]2, [(2-aminopyrimidine)2MnBr2(H2O)2·2H2O and (2-aminopyrimidinium)2+[MnBr2(H2O)4]Br2Journal of Coordination Chemistry, 56
-
G. Sheldrick (2008)
A short history of SHELX.Acta crystallographica. Section A, Foundations of crystallography, 64 Pt 1
-
Y. Kokunov, Yu. Gorbunova, V. Kovalev (2009)
Ribbon structure of the coordination polymer of silver trifluoroacetate with 2-pyrimidinecarboxamideRussian Journal of Inorganic Chemistry, 54
-
Y. Kokunov, Yu. Gorbunova (2007)
Influence of synthesis conditions on the properties of 2-pyrimidinecarbonitrile in complexing reactions: Synthesis and structure of the coordination polymer [Ag(C4H3N2CN)NO3] and mononuclear complex [Ag(C4H3N2COOH)2]NO3·H2ORussian Journal of Inorganic Chemistry, 52
-
Yueh-Hua Wang, K. Chu, Huan-Ching Chen, Chun‐Wei Yeh, Zhi-Kai Chan, Maw-Cherng Suen, J. Chen, Ju-chun Wang (2006)
Adjusting the frameworks of polymeric silver(I) complexes with 2-aminopyrimidyl ligands by changing the counterionsCrystEngComm, 8
-
J. Navarro, E. Barea, Miguel Galindo, J. Salas, M. Romero, M. Quirós, N. Masciocchi, S. Galli, A. Sironi, B. Lippert (2005)
Soft Functional Polynuclear Coordination Compounds Containing Pyrimidine BridgesChemInform, 36
- Publisher
- Springer Journals
- Copyright
- Copyright © 2015 by Pleiades Publishing, Ltd.
- Subject
- Chemistry; Physical Chemistry; Inorganic Chemistry
- ISSN
- 1070-3284
- eISSN
- 1608-3318
- DOI
- 10.1134/S1070328415120027
- Publisher site
- See Article on Publisher Site
Abstract
Coordination compound [CdI2(Ampym)2] is synthesized by the reaction of 2-amino-4-methylpyrimidine (Ampym, C5H7N3) with CdI2 in an acetonitrile–ethanol (20 : 1) mixture, and its crystal structure is determined. The crystals are triclinic, space group P $$\overline 1 $$ , a = 6.241(1), b = 11.929(1), c = 12.259(1) Å, α = 81.78(1)°, β = 78.82(1)°, γ = 75.82(1)°, V = 863.6(2) Å3, ρcalcd = 2.248 g/cm3, Z = 2. The cadmium atom has a tetrahedral coordination by two nitrogen atoms of crystallographically nonequivalent ligands L and two iodine atoms (Cd(1)–Nav 2.305(6), Cd(1)–I(1) 2.7093(8), and Cd(1)–I(2) 2.7235(7) Å). The angles at the Cd atom are 100.8(2)°–124.51(3)° (the maximum value corresponds to the ICdI angle). The planar rings N2C4 (±0.01 Å) of coordinated ligands L are arranged at an angle of 84.8° relatively to each other. The complexes are joined by hydrogen bonds N–H⋯N into zigzag supramolecular chains.
Journal
Russian Journal of Coordination Chemistry – Springer Journals
Published: Nov 22, 2015