Substitution of transition metal ions into aluminophosphates and silicoaluminophosphates: characterization and relation to catalysis

Substitution of transition metal ions into aluminophosphates and silicoaluminophosphates:... The literature related to the incorporation of transition metal ions (TMI) into aluminophosphate (AlPO) and silicoaluminophosphate (SAPO) molecular sieves is reviewed. Microporous crystalline metal aluminophosphates (MeAPOs) and metal silicoaluminophosphates (MeAPSOs) represent an important group of inorganic materials because of their high potential as adsorbents and catalysts. This review focuses mainly on the spectroscopic characterization of TMI containing MeAPOs and MeAPSOs covering the literature through 2000. The characterization of these materials is summarized and discussed in the light of possible isomorphous substitution of transition metal ions into the aluminophosphate framework. Moreover, the literature devoted to the use of these materials in catalysis and adsorption is reviewed. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Substitution of transition metal ions into aluminophosphates and silicoaluminophosphates: characterization and relation to catalysis

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Publisher
Brill Academic Publishers
Copyright
Copyright © 2002 by VSP 2002
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1163/15685670260469357
Publisher site
See Article on Publisher Site

Abstract

The literature related to the incorporation of transition metal ions (TMI) into aluminophosphate (AlPO) and silicoaluminophosphate (SAPO) molecular sieves is reviewed. Microporous crystalline metal aluminophosphates (MeAPOs) and metal silicoaluminophosphates (MeAPSOs) represent an important group of inorganic materials because of their high potential as adsorbents and catalysts. This review focuses mainly on the spectroscopic characterization of TMI containing MeAPOs and MeAPSOs covering the literature through 2000. The characterization of these materials is summarized and discussed in the light of possible isomorphous substitution of transition metal ions into the aluminophosphate framework. Moreover, the literature devoted to the use of these materials in catalysis and adsorption is reviewed.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Oct 13, 2004

References

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