Nanoporous and nanotubular titanium layers have been obtained via electrolytic etching in a mixed organic-inorganic electrolyte. The formation of layers has been studied in situ by electrochemical impedance spectroscopy. It has been shown that the impedance of an electrochemical cell is governed by the impedance of the contact between the electrolyte and titanium at the bottom of nanoporous and nanotubular layers almost throughout the entire process except the initial period. It has been revealed that the electrical resistance of the space charge region in a titanium layer is higher than the charge transfer resistance at the electrolyte/TiO x interface. This indicates that the rate of the growth of porous and nanotubular layers obtained via etching in an organic-inorganic electrolyte is limited by the transfer of titanium and oxygen ions through an oxide layer instead of the diffusion of ions in the electrolyte.
Russian Microelectronics – Springer Journals
Published: Nov 14, 2013
It’s your single place to instantly
discover and read the research
that matters to you.
Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.
All for just $49/month
Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly
Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.
Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.
Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.
All the latest content is available, no embargo periods.
“Hi guys, I cannot tell you how much I love this resource. Incredible. I really believe you've hit the nail on the head with this site in regards to solving the research-purchase issue.”Daniel C.
“Whoa! It’s like Spotify but for academic articles.”@Phil_Robichaud
“I must say, @deepdyve is a fabulous solution to the independent researcher's problem of #access to #information.”@deepthiw
“My last article couldn't be possible without the platform @deepdyve that makes journal papers cheaper.”@JoseServera