Study of the histamine copper(II) chloride complex catalytic activity

Study of the histamine copper(II) chloride complex catalytic activity The histamine (His) copper(II) chloride complex Cu(His)Cl2 was synthesized. Its octahedral geometry was confirmed by spectroscopic and X-rays methods. The catalytic activities of the Cu(His)Cl2 complex and the in situ generated copper(II) complexes were evaluated in the oxidation of catechol to o-quinone under atmospheric oxygen. The oxidation rates depend on the nature of the ion salts. A kinetic study revealed that the Cu(His)Cl2 complex has the highest oxidation rate compared to the in situ-formed one. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Study of the histamine copper(II) chloride complex catalytic activity

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Publisher
Springer Netherlands
Copyright
Copyright © 2013 by Springer Science+Business Media Dordrecht
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-013-1314-x
Publisher site
See Article on Publisher Site

Abstract

The histamine (His) copper(II) chloride complex Cu(His)Cl2 was synthesized. Its octahedral geometry was confirmed by spectroscopic and X-rays methods. The catalytic activities of the Cu(His)Cl2 complex and the in situ generated copper(II) complexes were evaluated in the oxidation of catechol to o-quinone under atmospheric oxygen. The oxidation rates depend on the nature of the ion salts. A kinetic study revealed that the Cu(His)Cl2 complex has the highest oxidation rate compared to the in situ-formed one.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Jun 27, 2013

References

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