Study of carbon dioxide adsorption on chromium oxide and gallium oxide catalysts on the basis of linear relaxation times

Study of carbon dioxide adsorption on chromium oxide and gallium oxide catalysts on the basis of... Results of nonstationary experiments on linear relaxation times were used to determine the rates of carbon dioxide adsorption and desorption on chromium oxide and gallium oxide catalysts by various mechanisms. The rate constants were used to calculate nonstationary concentrations of carbon dioxide on the assumption of linear, dissociative, and bimolecular adsorption–desorption mechanisms. A comparison of the calculated and experimental concentrations of carbon dioxide led to a conclusion that the process of its adsorption most probably occurs by the dissociative mechanism. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Study of carbon dioxide adsorption on chromium oxide and gallium oxide catalysts on the basis of linear relaxation times

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Publisher
Pleiades Publishing
Copyright
Copyright © 2016 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427216050062
Publisher site
See Article on Publisher Site

Abstract

Results of nonstationary experiments on linear relaxation times were used to determine the rates of carbon dioxide adsorption and desorption on chromium oxide and gallium oxide catalysts by various mechanisms. The rate constants were used to calculate nonstationary concentrations of carbon dioxide on the assumption of linear, dissociative, and bimolecular adsorption–desorption mechanisms. A comparison of the calculated and experimental concentrations of carbon dioxide led to a conclusion that the process of its adsorption most probably occurs by the dissociative mechanism.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Aug 12, 2016

References

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