Structures of photo-produced transient species

Structures of photo-produced transient species An overview of recent advances in the experimental measurements, theoretical interpretations, and practical applications of bond length and bond angle changes that occur after a molecule absorbs one or more photons is presented. “Gentle” changes are those in which the chemical bonds remain intact, but the lengths and angles increase or decrease. The bond length and bond angle changes that occur when a molecule absorbs a photon are measured by using a combination of electronic (emission and absorption) spectroscopy, resonance Raman spectroscopy, and the time-dependent theory of spectroscopy. “Catastrophic” changes are those in which multiple bonds are broken, leading to extensive photofragmentation. Luminescence spectroscopy is used to identify the transient fragments of metal-containing compounds that are precursors for laser assisted chemical vapor deposition. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Structures of photo-produced transient species

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Publisher
Springer Netherlands
Copyright
Copyright © 2000 by Springer
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1163/156856700X00101
Publisher site
See Article on Publisher Site

Abstract

An overview of recent advances in the experimental measurements, theoretical interpretations, and practical applications of bond length and bond angle changes that occur after a molecule absorbs one or more photons is presented. “Gentle” changes are those in which the chemical bonds remain intact, but the lengths and angles increase or decrease. The bond length and bond angle changes that occur when a molecule absorbs a photon are measured by using a combination of electronic (emission and absorption) spectroscopy, resonance Raman spectroscopy, and the time-dependent theory of spectroscopy. “Catastrophic” changes are those in which multiple bonds are broken, leading to extensive photofragmentation. Luminescence spectroscopy is used to identify the transient fragments of metal-containing compounds that are precursors for laser assisted chemical vapor deposition.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Jul 7, 2009

References

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