Structure and spectral properties of phenyldiazonium tetrachlorocuprate (II)

Structure and spectral properties of phenyldiazonium tetrachlorocuprate (II) Optimized equilibrium structure of phenyldiazonium tetrachlorocuprate(II) and its vibrational spectra were studied by performing quantum-chemical calculations by the B3LYP/6-31G(d,p) density functional method. A comparison with the isolated phenyldiazonium cation was made. An orbital structure of phenyldiazonium tetrachlorocuprate(II) is suggested to account for the activity of compounds of this kind as effective arylating reagents for olefins under the Meerwein reaction conditions. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Structure and spectral properties of phenyldiazonium tetrachlorocuprate (II)

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Publisher
SP MAIK Nauka/Interperiodica
Copyright
Copyright © 2010 by Pleiades Publishing, Ltd.
Subject
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427210010088
Publisher site
See Article on Publisher Site

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