A polymeric ethyne-hexacarbonyldicobalt π complex was prepared by the reaction of poly-p-diethynylbenzene with Co2(CO)8. The conformations in which the polymer chains can exist and the conformations in which the −C≡CH and-Ph-groups can form π complexes with Co2(CO)8 were revealed by analysis of Stuart-Briegleb molecular models. The IR spectra of the polymeric complexes were analyzed, and their thermal degradation in air was examined.
Russian Journal of Applied Chemistry – Springer Journals
Published: Dec 27, 2007
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