Stereoselectivity of electroreduction of a menthone-isomenthone mixture

Stereoselectivity of electroreduction of a menthone-isomenthone mixture Electroreduction of an equilibrium menthone-isomenthone mixture at a controlled potential in a diaphragm cell on various cathodes was studied. The influence exerted by the nature of a solvent and of an electrode, electrode material, and various additives on the reduction stereoselectivity of ketones was examined. Conditions for a predominant formation of the most stable of the four isomeric alcohols being formed, menthol, were found. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Stereoselectivity of electroreduction of a menthone-isomenthone mixture

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Publisher
SP MAIK Nauka/Interperiodica
Copyright
Copyright © 2009 by Pleiades Publishing, Ltd.
Subject
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427209070143
Publisher site
See Article on Publisher Site

Abstract

Electroreduction of an equilibrium menthone-isomenthone mixture at a controlled potential in a diaphragm cell on various cathodes was studied. The influence exerted by the nature of a solvent and of an electrode, electrode material, and various additives on the reduction stereoselectivity of ketones was examined. Conditions for a predominant formation of the most stable of the four isomeric alcohols being formed, menthol, were found.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Aug 25, 2009

References

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