The statistical ensembles of supramolecular formations (microdomains) on the surface of films of the polyamido acid derived from pyromellitic dianhydride and 4,4'-oxydiphenylenediamine and evolution of these ensembles in the course of thermal and chemical imidization were studied using the reversible aggregation model. The regular trends in variation of the distribution parameters (aggregation energy and mean microdomain size) in the course of thermal imidization were established. The distribution parameters were compared for polyimide films prepared by thermal and chemical imidization.
Russian Journal of Applied Chemistry – Springer Journals
Published: Oct 17, 2004
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