State and stability of 1H-hexakis(4-tert-butylphenyl)triazoleporphyrazine in proton-donor media

State and stability of 1H-hexakis(4-tert-butylphenyl)triazoleporphyrazine in proton-donor media The acid-base interaction of (1H-hexakis(4-tert-butylphenyl)triazoleporphyrazine in a benzeneacetic acid medium is studied. The structure and thermodynamic stability of the acidic form of this triazoleporphyrazine are determined. The reaction of the macrocycle destruction in a benzene-acetic acid medium is studied. The scheme for this reaction is proposed, and its kinetic parameters are determined. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

State and stability of 1H-hexakis(4-tert-butylphenyl)triazoleporphyrazine in proton-donor media

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Publisher
Nauka/Interperiodica
Copyright
Copyright © 2006 by Pleiades Publishing, Inc.
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328406020072
Publisher site
See Article on Publisher Site

Abstract

The acid-base interaction of (1H-hexakis(4-tert-butylphenyl)triazoleporphyrazine in a benzeneacetic acid medium is studied. The structure and thermodynamic stability of the acidic form of this triazoleporphyrazine are determined. The reaction of the macrocycle destruction in a benzene-acetic acid medium is studied. The scheme for this reaction is proposed, and its kinetic parameters are determined.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Mar 4, 2006

References

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