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Spin trapping with phosphonothionesters. Part VI. * Phosphoryl- and thiophosphoryl-thionformates

Spin trapping with phosphonothionesters. Part VI. * Phosphoryl- and thiophosphoryl-thionformates Ethyl (diethoxyphosphoryl)thionformate, ethyl (diethoxythiophosphoryl) thionformate, ethyl (diethoxyphosphoryl)thiolformate, and ethyl (diethoxythiophosphoryl)thiolformate have been allowed to react with a variety of in situ generated free radicals. Spin adducts were observed by EPR with the two thionesters but not with thiolesters; even the former compounds, however, exhibited a remarkably lower reactivity than similarly substituted dithioesters. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Spin trapping with phosphonothionesters. Part VI. * Phosphoryl- and thiophosphoryl-thionformates

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References (40)

Publisher
Springer Journals
Copyright
Copyright © 2001 by VSP 2001
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry
ISSN
0922-6168
eISSN
1568-5675
DOI
10.1163/156856701317051752
Publisher site
See Article on Publisher Site

Abstract

Ethyl (diethoxyphosphoryl)thionformate, ethyl (diethoxythiophosphoryl) thionformate, ethyl (diethoxyphosphoryl)thiolformate, and ethyl (diethoxythiophosphoryl)thiolformate have been allowed to react with a variety of in situ generated free radicals. Spin adducts were observed by EPR with the two thionesters but not with thiolesters; even the former compounds, however, exhibited a remarkably lower reactivity than similarly substituted dithioesters.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Oct 13, 2004

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