Spectroscopic, thermal, non-isothermal decomposition kinetics and quantum chemical computational studies of Ni(II)- and Cu(II)-Schiff base complexes

Spectroscopic, thermal, non-isothermal decomposition kinetics and quantum chemical computational... Keywords Schiff base-metal complexes  Thermal studies  Non-isothermal kinetic parameters  Raman frequencies  DFT Introduction In the modern age, the introduction of sophisticated physicochemical techniques of higher accuracy and potential have greatly enriched our understanding to the nature of the metal–ligand bond, the structural features of metal complexes, their stability and other properties. The well-established thermogravimetry and differential scanning calorimetry techniques have been consistently used in studying the thermal behavior and properties of various types of materials for many years [1, 2]. In association with other characterization techniques like FTIR, PXRD, Mass; etc., thermal studies provide valuable structural information. Kinetic parameters of non- isothermal degradation steps of metal complexes obtained by thermoanalytical methods may be evaluated by several methods [3, 4]. The knowledge of the mechanism of non-isothermal degradation allows the postulation of kinetic equations or vice versa [5]. There are different methods to study the kinetics of non-isothermal processes including statistical methods [6, 7], methods for different reaction models, Coats–Redfern (C–R) [8], Piloyan–Novikova (P–N) [9], Horowitz–Metzger (H–M) [10], and iso-conversional model free methods [11]. In the last three decades, DFT has become the most popular and useful computational approach to predict fairly accurate structural information for http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Spectroscopic, thermal, non-isothermal decomposition kinetics and quantum chemical computational studies of Ni(II)- and Cu(II)-Schiff base complexes

Loading next page...
 
/lp/springer_journal/spectroscopic-thermal-non-isothermal-decomposition-kinetics-and-S6B7qwZG03
Publisher
Springer Journals
Copyright
Copyright © 2016 by Springer Science+Business Media Dordrecht
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-016-2722-5
Publisher site
See Article on Publisher Site

Abstract

Keywords Schiff base-metal complexes  Thermal studies  Non-isothermal kinetic parameters  Raman frequencies  DFT Introduction In the modern age, the introduction of sophisticated physicochemical techniques of higher accuracy and potential have greatly enriched our understanding to the nature of the metal–ligand bond, the structural features of metal complexes, their stability and other properties. The well-established thermogravimetry and differential scanning calorimetry techniques have been consistently used in studying the thermal behavior and properties of various types of materials for many years [1, 2]. In association with other characterization techniques like FTIR, PXRD, Mass; etc., thermal studies provide valuable structural information. Kinetic parameters of non- isothermal degradation steps of metal complexes obtained by thermoanalytical methods may be evaluated by several methods [3, 4]. The knowledge of the mechanism of non-isothermal degradation allows the postulation of kinetic equations or vice versa [5]. There are different methods to study the kinetics of non-isothermal processes including statistical methods [6, 7], methods for different reaction models, Coats–Redfern (C–R) [8], Piloyan–Novikova (P–N) [9], Horowitz–Metzger (H–M) [10], and iso-conversional model free methods [11]. In the last three decades, DFT has become the most popular and useful computational approach to predict fairly accurate structural information for

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Sep 17, 2016

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Search

Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly

Organize

Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.

Access

Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve

Freelancer

DeepDyve

Pro

Price

FREE

$49/month
$360/year

Save searches from
Google Scholar,
PubMed

Create lists to
organize your research

Export lists, citations

Read DeepDyve articles

Abstract access only

Unlimited access to over
18 million full-text articles

Print

20 pages / month

PDF Discount

20% off