Access the full text.
Sign up today, get DeepDyve free for 14 days.
U. Lohse, R. Bertram, K. Jancke, I. Kurzawski, B. Parlitz, Elke Löuffler, E. Schreier (1995)
Acidity of aluminophosphate structures. Part 2.—Incorporation of cobalt into CHA and AFI by microwave synthesisJournal of the Chemical Society, Faraday Transactions, 91
Sang-Eon Park, D. Kim, Jong‐San Chang, W. Kim (1998)
Photoluminescence spectroscopic monitoring in the synthesis of mesoporous materials by microwave-induced heatingStudies in Surface Science and Catalysis, 117
S. Inagaki, Y. Fukushima, K. Kuroda (1993)
Synthesis of highly ordered mesoporous materials from a layered polysilicateJournal of The Chemical Society, Chemical Communications
A. Romero, M. Alba, Wuzong Zhou, J. Klinowski (1997)
Synthesis and Characterization of the Mesoporous Silicate Molecular Sieve MCM-48Journal of Physical Chemistry B, 101
Chun‐Guey Wu, T. Bein (1996)
Microwave synthesis of molecular sieve MCM-41Chemical Communications
J. Beck, J. Vartuli (1996)
Recent advances in the synthesis, characterization and applications of mesoporous molecular sievesCurrent Opinion in Solid State & Materials Science, 1
H. Itoh, S. Ishido, M. Nomura, and Hayakawa, S. Mitaku (1996)
Estimation of the Hydrophobicity in Microenvironments by Pyrene Fluorescence Measurements: n-β-Octylglucoside MicellesThe Journal of Physical Chemistry, 100
C. Chen, S. Burkett, Hong-xin Li, Mark Davis (1993)
Studies on mesoporous materials II. Synthesis mechanism of MCM-41Microporous Materials, 2
M. Almgren, F. Grieser, J. Thomas (1980)
Photochemical and photophysical studies of organized assemblies. Interaction of oils, long-chain alcohols, and surfactants forming microemulsionsJournal of the American Chemical Society, 102
Griffith Oh, Libertini Lj, Birrell Gb (1971)
The role of lipid spin labels in membrane biophysics.The Journal of Physical Chemistry, 75
Jun Liu, A. Kim, J. Virden, B. Bunker (1995)
Effect of colloidal particles on the formation of ordered mesoporous materialsLangmuir, 11
G. Roussy, P. Chenot (1981)
Selective energy supply to adsorbed water and nonclassical thermal process during microwave dehydration of zeoliteThe Journal of Physical Chemistry, 12
A. Galameau, D. Lemer, M. Ottaviani, F. Renzo, F. Fajuia (1998)
EPR and UV-visible fluorescence spectroscopic evidences for intermediate phases during the formation of micelle-templated silicasStudies in Surface Science and Catalysis, 117
L. Skuja, A. Silin, A. Boganov (1984)
On the nature of the 1.9 eV luminescence centers in amorphous SiO2Journal of Non-crystalline Solids, 63
Jingyan Zhang, Z. Luz, D. Goldfarb (1997)
EPR Studies of the Formation Mechanism of the Mesoporous Materials MCM-41 and MCM-50Journal of Physical Chemistry B, 101
K. Kalyanasundaram, J. Thomas (1977)
Environmental effects on vibronic band intensities in pyrene monomer fluorescence and their application in studies of micellar systemsJournal of the American Chemical Society, 99
A. Sayari (1996)
Periodic mesoporous materials: synthesis, characterization and potential applicationsStudies in Surface Science and Catalysis, 102
I. Girnus, K. Jancke, R. Vetter, J. Richter-mendau, J. Caro (1995)
Large AlPO4-5 crystals by microwave heatingZeolites, 15
D. Calabro, E. Valyocsik, F. Ryan (1996)
In situ ATR/FTIR study of mesoporous silicate synthesesMicroporous Materials, 7
J. Thomas (1980)
Radiation-induced reactions in organized assembliesChemical Reviews, 80
A. Arafat, J. Jansen, A. Ebaid, H. Bekkum (1993)
Microwave preparation of zeolite Y and ZSM-5Zeolites, 13
C. Kwan, S. Atik, L. Singer (1978)
An electron spin resonance study of the association of a surfactant nitroxyl radical with a cationic micelle using spin-intensity measurements and hyperfine structure analysesJournal of the American Chemical Society, 100
Sang-Eon Park, D. Kim, Jong‐San Chang, W. Kim (1998)
Synthesis of MCM-41 using microwave heating with ethylene glycolCatalysis Today, 44
C. Kresge, M. Leonowicz, W. Roth, J. Vartuli, J. Beck (1992)
Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanismNature, 359
A. Monnier, Ferdi Schüth, Ferdi Schüth, Ferdi Schüth, Q. Huo, D. Kumar, D. Margolese, R. Maxwell, G. Stucky, M. Krishnamurty, Pierre Petroff, A. Firouzi, M. Janicke, B. Chmelka (1993)
Cooperative Formation of Inorganic-Organic Interfaces in the Synthesis of Silicate MesostructuresScience, 261
Yoon Lee, and Surjadi, J. Rathman (1996)
Effects of Aluminate and Silicate on the Structure of Quaternary Ammonium Surfactant AggregatesLangmuir, 12
A. Trukhin (1990)
Localized states of silicon dioxide, sodium and lead silicate glassesJournal of Non-crystalline Solids, 123
The mesoporous MCM-41 materials were prepared in very short crystallization time (∼40 min) upon microwave irradiation in comparison with conventional hydrothermal heating method. With both microwave irradiation and hydrothermal heating, the MCM-41 formation via supramolecular templating method has been monitored by fluorescence and electron spin resonance (ESR) spectroscopy. Pyrene as a fluorescence probe and 4-(N,N-dimethyl-N-hexadecyl)ammonium-2,2,6,6-tetramethyl piperidinyloxy iodide (CAT16) as a spin probe were respectively dissolved into the micelle solutions to form the MCM-41 precursor gels. These probes allow the monitoring of the supramolecular interaction between the anionic silicate species and the cationic surfactant molecules during the MCM-41 formation. Analyses of fluorescence and ESR spectra indicate that the fast increase of hydrophobicity and microviscosity at the solubilzation sites of the probes results from the accelerated condensation of silicates onto the micelle surface upon microwave irradiation. The fluorescence change from the silicate L-center in the MCM-41 precursor gel also probes the fast silicate condensation upon microwave irradiation. It seems that the fast formation of MCM-41 upon microwave irradiation is ascribed to the microwave-susceptible head groups of surfactant molecules in addition to fast dissolution of the precursor gel.
Research on Chemical Intermediates – Springer Journals
Published: Jan 1, 2000
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.