Specific process features of epoxidation of fatty acid methyl esters of vegetable oils with performic acid generated in situ

Specific process features of epoxidation of fatty acid methyl esters of vegetable oils with... Physicochemical relationships of the phase distribution of the reactants in epoxidation of fatty acid methyl esters of vegetable oils with performic acid generated in situ were determined.. The progress of epoxidation is accompanied by redistribution of the organic and aqueous phase volumes. The major cause of changes in the phase volumes is the transfer of peroxide oxygen from the aqueous phase into the organic phase upon formation of epoxy groups. A comparable change in the phase volumes is due to reactive extraction of aqueous phase components with the epoxy compounds formed. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Specific process features of epoxidation of fatty acid methyl esters of vegetable oils with performic acid generated in situ

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Publisher
Springer Journals
Copyright
Copyright © 2017 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427217010098
Publisher site
See Article on Publisher Site

Abstract

Physicochemical relationships of the phase distribution of the reactants in epoxidation of fatty acid methyl esters of vegetable oils with performic acid generated in situ were determined.. The progress of epoxidation is accompanied by redistribution of the organic and aqueous phase volumes. The major cause of changes in the phase volumes is the transfer of peroxide oxygen from the aqueous phase into the organic phase upon formation of epoxy groups. A comparable change in the phase volumes is due to reactive extraction of aqueous phase components with the epoxy compounds formed.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Apr 25, 2017

References

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