Results of a thermodynamic and geometric-topological analysis of the subsolidus structure of the BaO – Al2O3 – Fe2O3 – SiO2 system at temperatures above 1381 K are reported. Tetrahedratization of the system, with due regard for the existing high-temperature phases, is carried out. Data for solid-state reactions in the system obtained by thermodynamic and geometric-topological calculations are presented. Technological implications in the synthesis a new class of barium-containing cements with allowance for the specific subsolidus structure (associated with reversible solid-state reactions in ternary subsystems and the quaternary BaO – Al2O3 – Fe2O3 – SiO2 system proper) are discussed.
Refractories and Industrial Ceramics – Springer Journals
Published: Oct 17, 2004
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