Specific features of ethylene polymerization on self-immobilizing catalytic systems based on titanium bis(phenoxy imine) complexes

Specific features of ethylene polymerization on self-immobilizing catalytic systems based on... The kinetics of ethylene polymerization on six methylalumoxane-activated self-immobilizing bis(phenoxy imine) complexes of titanium chloride with allyloxy groups in the m- and p-positions of the N-phenyl ring and with various substituents in the salicylaldehyde fragment was studied. The activity of the complexes in the temperature range 20–60°C and ethylene pressure of 0.4 MPa was evaluated. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Specific features of ethylene polymerization on self-immobilizing catalytic systems based on titanium bis(phenoxy imine) complexes

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Publisher
SP MAIK Nauka/Interperiodica
Copyright
Copyright © 2011 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general ; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427211010204
Publisher site
See Article on Publisher Site

Abstract

The kinetics of ethylene polymerization on six methylalumoxane-activated self-immobilizing bis(phenoxy imine) complexes of titanium chloride with allyloxy groups in the m- and p-positions of the N-phenyl ring and with various substituents in the salicylaldehyde fragment was studied. The activity of the complexes in the temperature range 20–60°C and ethylene pressure of 0.4 MPa was evaluated.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Feb 19, 2011

References

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