Several fractions of diesel fuel recovered from Arlan crude oil were treated with hydrogen peroxide, and the sulfoxides formed by oxidation of petroleum sulfides were isolated with aqueous sulfuric acid. The water solubility of these sulfoxides and their limiting extraction capacity with respect to neodymium nitrate were determined. Correlations between several characteristics of the petroleum sulfoxides [water solubility, limiting extraction capacity with respect to neodymium(III) nitrate, phase separation time under standard conditions, and viscosity] and the boiling range of corresponding petroleum fractions were analyzed.
Russian Journal of Applied Chemistry – Springer Journals
Published: Oct 13, 2004
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