Solvolthermal synthesis, structure, and properties of a novel dinuclear zinc(II) complex

Solvolthermal synthesis, structure, and properties of a novel dinuclear zinc(II) complex A novel centrosymmetric dinuclear zinc(II) complex, [Zn2L2], was prepared from 2-bromo-6-[(3-cyclohexylaminopropylimino)methyl]phenol (H2L), 3,5-dichlorosalicylaldehyde, and zinc acetate under solvolthermal conditions. There occurs a rarely-seen 1,3-hydride shift reaction during the process. Structure of [Zn2L2] has been characterized by elemental analysis, IR spectra, and single crystal X-ray diffraction (CIF file CCDC no. 956057). The Zn⋯Zn separation is 3.163(1)°. Each Zn atom in the complex is in a trigonal-bipyramidal coordination. Thermal stability and fluorescence property of [Zn2L2] were studied. The complex displays intraligand π-π* fluorescence and can potentially serve as photoactive material. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Solvolthermal synthesis, structure, and properties of a novel dinuclear zinc(II) complex

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Publisher
Springer Journals
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328415060093
Publisher site
See Article on Publisher Site

Abstract

A novel centrosymmetric dinuclear zinc(II) complex, [Zn2L2], was prepared from 2-bromo-6-[(3-cyclohexylaminopropylimino)methyl]phenol (H2L), 3,5-dichlorosalicylaldehyde, and zinc acetate under solvolthermal conditions. There occurs a rarely-seen 1,3-hydride shift reaction during the process. Structure of [Zn2L2] has been characterized by elemental analysis, IR spectra, and single crystal X-ray diffraction (CIF file CCDC no. 956057). The Zn⋯Zn separation is 3.163(1)°. Each Zn atom in the complex is in a trigonal-bipyramidal coordination. Thermal stability and fluorescence property of [Zn2L2] were studied. The complex displays intraligand π-π* fluorescence and can potentially serve as photoactive material.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Jun 3, 2015

References

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