Sn–bentonite-induced Baeyer–Villiger oxidation of 2-heptylcyclopentanone to δ-dodecalactone with aqueous hydrogen peroxide

Sn–bentonite-induced Baeyer–Villiger oxidation of 2-heptylcyclopentanone to δ-dodecalactone... A tin ion-exchanged bentonite seems to be a rather efficient and highly selective catalyst for Baeyer–Villiger oxidation of 2-heptylcyclopentanone to δ-dodecalactone using aqueous hydrogen peroxide (35 wt%) as a clean oxidant. The bentonite-supported tin catalyst was characterized by IR spectroscopy, X-ray diffraction spectroscopy, and scanning electron microscopy. Methanesulfonic acid and sodium dodecyl sulfate promoted conversion of 2-heptylcyclopentanone to δ-dodecalactone in high (81 %) yield. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Sn–bentonite-induced Baeyer–Villiger oxidation of 2-heptylcyclopentanone to δ-dodecalactone with aqueous hydrogen peroxide

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Publisher
Springer Netherlands
Copyright
Copyright © 2013 by Springer Science+Business Media Dordrecht
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-013-1342-6
Publisher site
See Article on Publisher Site

Abstract

A tin ion-exchanged bentonite seems to be a rather efficient and highly selective catalyst for Baeyer–Villiger oxidation of 2-heptylcyclopentanone to δ-dodecalactone using aqueous hydrogen peroxide (35 wt%) as a clean oxidant. The bentonite-supported tin catalyst was characterized by IR spectroscopy, X-ray diffraction spectroscopy, and scanning electron microscopy. Methanesulfonic acid and sodium dodecyl sulfate promoted conversion of 2-heptylcyclopentanone to δ-dodecalactone in high (81 %) yield.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Jul 30, 2013

References

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