Semiconductor photocatalysis type B: synthesis of unsaturated α-cyano-homoallylamines from imines and olefins photocatalysed by silica- and cellulose-supported cadmium sulphide

Semiconductor photocatalysis type B: synthesis of unsaturated α-cyano-homoallylamines from... α-Cyano-homoallylamines are synthesised in moderate yields by the photocatalysed linear addition of olefins to Ph(CN)C=NPh in the presence of silica-supported cadmium sulphide. Band edge positions of cadmium sulphide and the rate and diastereoselectivity of this radical C-C coupling reaction are not significantly changed when the semiconductor is supported onto cellulose. The latter result is in accordance with the absence of covalent semiconductor-support interactions. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Semiconductor photocatalysis type B: synthesis of unsaturated α-cyano-homoallylamines from imines and olefins photocatalysed by silica- and cellulose-supported cadmium sulphide

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Publisher
Springer Netherlands
Copyright
Copyright © 2007 by Springer
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1163/156856707779238595
Publisher site
See Article on Publisher Site

Abstract

α-Cyano-homoallylamines are synthesised in moderate yields by the photocatalysed linear addition of olefins to Ph(CN)C=NPh in the presence of silica-supported cadmium sulphide. Band edge positions of cadmium sulphide and the rate and diastereoselectivity of this radical C-C coupling reaction are not significantly changed when the semiconductor is supported onto cellulose. The latter result is in accordance with the absence of covalent semiconductor-support interactions.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Apr 15, 2009

References

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