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α-Cyano-homoallylamines are synthesised in moderate yields by the photocatalysed linear addition of olefins to Ph(CN)C=NPh in the presence of silica-supported cadmium sulphide. Band edge positions of cadmium sulphide and the rate and diastereoselectivity of this radical C-C coupling reaction are not significantly changed when the semiconductor is supported onto cellulose. The latter result is in accordance with the absence of covalent semiconductor-support interactions.
Research on Chemical Intermediates – Springer Journals
Published: Apr 15, 2009
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