Two new complexes [Co(Pdon)(SCN)2(H2O)2] (I) and [Hg(Pdon)2Br2] (II) (Pdon = 1,10-phenanthroline-5,6-dione) have been synthesized and characterized by element analysis, IR and single crystal X-ray diffraction (CIF files CCDC nos. 793904 (I) and 783209 (II)). Compounds I and II are mononuclear complexes obtained by the self-assembly of Pdon, SCN− and metal ion Co2+ and Hg2+, which are further in close contacted forming a two dimensional supramolecular framework via O-H⋯S and O-H⋯O hydrogen bonding interactions interactions between adjacent molecules.
Russian Journal of Coordination Chemistry – Springer Journals
Published: Jun 24, 2015
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