Self-aggregation of synthetic zinc 31-hydroxy-131-oxo-17,18-cis-chlorin in a non-polar organic solvent

Self-aggregation of synthetic zinc 31-hydroxy-131-oxo-17,18-cis-chlorin in a non-polar organic... Zinc methyl 31-demethyl-17,18-cis-bacteriopheophorbide-d was prepared as a model of naturally occurring bacteriochlorophyll-d. From the absorption spectral analysis, the synthetic cis-chlorin self-aggregated in a non-polar organic solvent to give an oligomer possessing red-shifted and broadened peaks, compared to the non-aggregated form. The red-shifted values by self-aggregation were smaller than those observed in the corresponding trans-isomer, indicating that self-aggregates of the cis-isomer took on more disordered supramolecular structures than those of the trans-isomer. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Self-aggregation of synthetic zinc 31-hydroxy-131-oxo-17,18-cis-chlorin in a non-polar organic solvent

Loading next page...
 
/lp/springer_journal/self-aggregation-of-synthetic-zinc-31-hydroxy-131-oxo-17-18-cis-rur0hWmhG8
Publisher
Springer Netherlands
Copyright
Copyright © 2007 by Springer
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1163/156856707779160915
Publisher site
See Article on Publisher Site

Abstract

Zinc methyl 31-demethyl-17,18-cis-bacteriopheophorbide-d was prepared as a model of naturally occurring bacteriochlorophyll-d. From the absorption spectral analysis, the synthetic cis-chlorin self-aggregated in a non-polar organic solvent to give an oligomer possessing red-shifted and broadened peaks, compared to the non-aggregated form. The red-shifted values by self-aggregation were smaller than those observed in the corresponding trans-isomer, indicating that self-aggregates of the cis-isomer took on more disordered supramolecular structures than those of the trans-isomer.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Apr 25, 2009

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 12 million articles from more than
10,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Unlimited reading

Read as many articles as you need. Full articles with original layout, charts and figures. Read online, from anywhere.

Stay up to date

Keep up with your field with Personalized Recommendations and Follow Journals to get automatic updates.

Organize your research

It’s easy to organize your research with our built-in tools.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve Freelancer

DeepDyve Pro

Price
FREE
$49/month

$360/year
Save searches from
Google Scholar,
PubMed
Create lists to
organize your research
Export lists, citations
Read DeepDyve articles
Abstract access only
Unlimited access to over
18 million full-text articles
Print
20 pages/month
PDF Discount
20% off