Selective oxidation of hydrocarbons catalyzed by iron-containing heterogeneous catalysts

Selective oxidation of hydrocarbons catalyzed by iron-containing heterogeneous catalysts Recent studies on iron-based heterogeneous catalysts for selective oxidation of hydrocarbons are reviewed with emphasis on the partial oxidation of methane and the epoxidation of alkenes. High dispersion of iron sites is essentially important for the selective oxidations. The effective catalysts include immobilized or encapsulated iron complexes, iron-doped metal oxides such as Fe3+-doped silica, iron-containing microporous and mesoporous materials, and iron-containing compounds with isolated iron sites typified by iron phosphate. The structure-reactivity relationships and the factors affecting the catalytic performances are discussed with the aim to uncover the requirements of the active iron sites in target-selective oxidation. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Selective oxidation of hydrocarbons catalyzed by iron-containing heterogeneous catalysts

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Publisher
Springer Netherlands
Copyright
Copyright © 2006 by Springer
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1163/156856706777346426
Publisher site
See Article on Publisher Site

Abstract

Recent studies on iron-based heterogeneous catalysts for selective oxidation of hydrocarbons are reviewed with emphasis on the partial oxidation of methane and the epoxidation of alkenes. High dispersion of iron sites is essentially important for the selective oxidations. The effective catalysts include immobilized or encapsulated iron complexes, iron-doped metal oxides such as Fe3+-doped silica, iron-containing microporous and mesoporous materials, and iron-containing compounds with isolated iron sites typified by iron phosphate. The structure-reactivity relationships and the factors affecting the catalytic performances are discussed with the aim to uncover the requirements of the active iron sites in target-selective oxidation.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Apr 15, 2009

References

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