Selective oxidation of alcohols using ferrocene-labeled Merrifield resin-supported ionic liquid phase catalysts

Selective oxidation of alcohols using ferrocene-labeled Merrifield resin-supported ionic liquid... & Gajanan Rashinkar gsr_chem@unishivaji.ac.in Department of Chemistry, Shivaji University, Kolhapur, M.S. 416004, India 123 7808 R. Kurane et al. Keywords Merrifield resin  Selective oxidation  Alcohols  Ferrocene  Reusability Introduction Selective oxidation of alcohols into aldehydes is a ubiquitous and pivotal process in organic chemistry [1–4]. Traditionally, high-valent metal oxides of chromium, manganese and ruthenium are widely employed for this purpose [5–8]. Insights into these homogeneous catalytic systems have revealed some serious problems, such as over-oxidation of aldehydes to carboxylic acid, the use of hazardous terminal oxidants, drastic reaction conditions, tedious work-up procedures and generation of significant amounts of toxic waste products. The covalent immobilization of these reagents on solid supports has been carried out to alleviate aforementioned problems and provide an attractive alternative in organic synthesis in view of the selectivity and associated ease of manipulation [9–14]. A variety of other reagents, such as oxone [15], calcium hypochlorite [16], 2-hydroperoxyhexafluoro-2-propanol [17], vanadium [18], Cu-NHC-TEMPO [19], nano structured rutile TiO [20], palladium [21], choline peroxydisulphate [22], nickel phosphine complexes [23], In(NO ) in 3 3 [C mim][FeBr ][24], derivatives of 1-acetoxy-1,2-benziodoxole-3(1H)-one [25], 12 4 sym-collidinium chlorochromate (S-COCC) [26], Ag-NHC complex [27], etc. have been used for selective http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Selective oxidation of alcohols using ferrocene-labeled Merrifield resin-supported ionic liquid phase catalysts

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Publisher
Springer Netherlands
Copyright
Copyright © 2016 by Springer Science+Business Media Dordrecht
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-016-2563-2
Publisher site
See Article on Publisher Site

Abstract

& Gajanan Rashinkar gsr_chem@unishivaji.ac.in Department of Chemistry, Shivaji University, Kolhapur, M.S. 416004, India 123 7808 R. Kurane et al. Keywords Merrifield resin  Selective oxidation  Alcohols  Ferrocene  Reusability Introduction Selective oxidation of alcohols into aldehydes is a ubiquitous and pivotal process in organic chemistry [1–4]. Traditionally, high-valent metal oxides of chromium, manganese and ruthenium are widely employed for this purpose [5–8]. Insights into these homogeneous catalytic systems have revealed some serious problems, such as over-oxidation of aldehydes to carboxylic acid, the use of hazardous terminal oxidants, drastic reaction conditions, tedious work-up procedures and generation of significant amounts of toxic waste products. The covalent immobilization of these reagents on solid supports has been carried out to alleviate aforementioned problems and provide an attractive alternative in organic synthesis in view of the selectivity and associated ease of manipulation [9–14]. A variety of other reagents, such as oxone [15], calcium hypochlorite [16], 2-hydroperoxyhexafluoro-2-propanol [17], vanadium [18], Cu-NHC-TEMPO [19], nano structured rutile TiO [20], palladium [21], choline peroxydisulphate [22], nickel phosphine complexes [23], In(NO ) in 3 3 [C mim][FeBr ][24], derivatives of 1-acetoxy-1,2-benziodoxole-3(1H)-one [25], 12 4 sym-collidinium chlorochromate (S-COCC) [26], Ag-NHC complex [27], etc. have been used for selective

Journal

Research on Chemical IntermediatesSpringer Journals

Published: May 17, 2016

References

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