Regioselectivity of the insertion of RNSO(S) and RCN into the M–L bonds of the tungsten chlorocomplexes

Regioselectivity of the insertion of RNSO(S) and RCN into the M–L bonds of the tungsten... The results of studying the reaction behavior of tungsten hexachloride toward organic iso(thio)cyanates and their combinations with nitriles are generalized. The factors determining the multiplet insertion of iso(thio)cyanates at the W–Cl bond and the conditions of symmetrical or asymmetrical crosslinking of the inserted fragments into heterocycles upon their trimerization (on the basis of the X-ray structural data on the products of the partial or complete hydrolysis of the complexes) are discussed. The reasons determining the direction of the combined insertion of heterocumulenes and nitriles at the W–Cl or W–N bond are considered, which is important for the targeted design of complexes of various architecture and new poorly accessible related heterocyclic compounds. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Regioselectivity of the insertion of RNSO(S) and RCN into the M–L bonds of the tungsten chlorocomplexes

Loading next page...
 
/lp/springer_journal/regioselectivity-of-the-insertion-of-rnso-s-and-rcn-into-the-m-l-bonds-8uh20qGsBm
Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328415090031
Publisher site
See Article on Publisher Site

Abstract

The results of studying the reaction behavior of tungsten hexachloride toward organic iso(thio)cyanates and their combinations with nitriles are generalized. The factors determining the multiplet insertion of iso(thio)cyanates at the W–Cl bond and the conditions of symmetrical or asymmetrical crosslinking of the inserted fragments into heterocycles upon their trimerization (on the basis of the X-ray structural data on the products of the partial or complete hydrolysis of the complexes) are discussed. The reasons determining the direction of the combined insertion of heterocumulenes and nitriles at the W–Cl or W–N bond are considered, which is important for the targeted design of complexes of various architecture and new poorly accessible related heterocyclic compounds.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Sep 2, 2015

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 12 million articles from more than
10,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Unlimited reading

Read as many articles as you need. Full articles with original layout, charts and figures. Read online, from anywhere.

Stay up to date

Keep up with your field with Personalized Recommendations and Follow Journals to get automatic updates.

Organize your research

It’s easy to organize your research with our built-in tools.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve Freelancer

DeepDyve Pro

Price
FREE
$49/month

$360/year
Save searches from Google Scholar, PubMed
Create lists to organize your research
Export lists, citations
Access to DeepDyve database
Abstract access only
Unlimited access to over
18 million full-text articles
Print
20 pages/month
PDF Discount
20% off