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References (22)
-
N. Ovchinnikova, A. Sinyakov, A. Reznik, S. Sakharov, Yu. Gorbunova, Yu. Mikhaǐlov, A. Kanishcheva, V. Butskii (2002)
Insertion of Ethyl Isocyanate at the Tungsten–Chlorine Bond. Crystal Structure of 1,3,5-Triethyl-1,3,5-triazine-2,4,6-(1H,3H,5H)-trioneRussian Journal of Coordination Chemistry, 28
-
(1982)
Uvod do studia Organické chemie, Praha: Nakladatelstvi technicke literatury -
C. Broder, A. Goeta, J. Howard, A. Hughes, A. Johnson, J. Malget, K. Wade (2000)
Insertion and cleavage reactions of [closo-3,1,2-Ta(NMe2)3(C2B9H11)] with nitriles, phenols and thiols; structural characterisation of N,N-dimethylamidinate ligandsJournal of The Chemical Society-dalton Transactions
-
C. Afonso, N. Lourenço, Andreia Rosatella (2006)
Synthesis of 2,4,6-tri-substituted-1,3,5-triazines.Molecules, 11 1
-
G. Fowles, D. Rice, K. Shanton (1977)
Reaction of some aliphatic and aromatic nitriles with tungsten(VI) chloride leading to the formation of tungsten–nitrogen multiply bonded compoundsJournal of The Chemical Society-dalton Transactions
-
A. Batsanov, A. Goeta, J. Howard, A. Hughes, A. Johnson, K. Wade (2001)
Tungsten(VI) metallacarborane imido complexes; hydrogen bonding to a bent imido ligand in {W(NtBu)2[N(H)C(Me)NHtBu](C2B9H11)}Journal of The Chemical Society-dalton Transactions
-
D. Ballivet-Tkatchenko, H. Chermette, L. Plasserauda (2006)
Dalton Trans. -
N. Ovchinnikova, A. Sinyakov, V. Sergienko, G. Alexandrov, M. Burtzev (2003)
Triple Insertion of Ethylisocyanate into A W-Cl Bond and its Inner-Sphere Cyclization. Crystal Structure of Tetrachlorooxo (3,5-Diethyl- 2-Methylamino[1,3,5]-Oxadiazine- 2,4-Dione)Tungsten(VI)Journal of Coordination Chemistry, 56
-
Eva Hevia, Julio Pérez, V. Riera, D. Miguel (2002)
New octahedral rhenium(I) tricarbonyl amido complexesOrganometallics, 21
-
M. Lappert, A. Sanger (1971)
Amido-derivatives of metals and metalloids. Part XIV. Reactions of titanium(III) dimethylamides with protic or unsaturated reagents, or with metal hydridesJournal of The Chemical Society A: Inorganic, Physical, Theoretical
-
M. Dinger, W. Henderson (1998)
Insertion reactions of platinum(II) ureylene complexesJournal of The Chemical Society-dalton Transactions
-
A. Sinyakov, G. Aleksandrov, N. Ovchinnikova (2004)
Synthesis and crystal structure of trans-tetrachloro(C, C-dichloro-C-phenyl-methyl-nitrido)(phenylnitrilo)tungsten(VI), trans-[WCl4(NCCl2Ph)(NCPh)]Crystallography Reports, 49
-
N. Ovchinnikova, A. Sinyakov (2006)
Heteromolecular insertion of EtNCX (X = O, S) and RCN (R = CH3, C6H5) into tungsten hexachlorideRussian Journal of Coordination Chemistry, 32
-
N. Ovchinnikova, A. Sinyakov, A. Streletskii, N. Polyakov (2004)
Composition and Structure of [WCl4{N(Et)C(O)}3Cl]: MALDI-TOF Mass Spectrometric StudyRussian Journal of Coordination Chemistry, 30
-
D. Morrison, D. Wigley (1995)
MULTIPLE-IMIDO COMPLEXES OF MOLYBDENUM : SYNTHESIS AND REACTIVITY OF THE D0 MO(=NR)3 FUNCTIONAL GROUPInorganic Chemistry, 34
-
R. Bohra, A. Rai, R. Mehrotra (1977)
N-aryl alkyl carbamate derivatives of Ta(V)Inorganica Chimica Acta, 25
-
R. Mehrotra, A. Rai, R. Bohra (1974)
Insertion reactions of niobium alkoxides with phenylisocyanateJournal of Inorganic and Nuclear Chemistry, 36
-
N. Ovchinnikova, A. Sinyakov, V. Sergienko, G. Aleksandrov (2003)
Insertion of ethyl isothiocyanate into tungsten hexachloride: Crystal structure of ethyl-(4-ethyl-5-thioxo[1.2.4]dithiazolidin-3-ylidene)ammonium oxopentachlorotungstate(VI)Crystallography Reports, 48
-
Mahbobeh Behnam-Dehkordy, B. Crociani, M. Nicolini, R. Richards (1979)
The reactions of t-BuNC with halides of Titanium(IV), Hafnium(IV), Vanadium(III), Niobium(IV), Molybdenum(V) and Tungsten(VI); insertion into metal—halogen bonds and ligand displacement reactionsJournal of Organometallic Chemistry, 181
-
P. Braunstein, D. Nobel (1989)
Chem. Rev. -
P. Legzdins, S. Rettig, K. Ross (1994)
Competitive Reactivity of W-C, W-N, and W-O Bonds at the Cp*W(NO) Fragment: Insertion Reactions of tert-Butyl Isocyanide, p-Tolyl Isocyanate, and Carbon DisulfideOrganometallics, 13
-
M. Drew, K. Moss, N. Rolfe (1971)
Crystal structure of tetrachloro(trichloro-acetonitrile)pentachloroethylnitrido-tungsten(VI)Inorganic and Nuclear Chemistry Letters, 7
- Publisher
- Springer Journals
- Copyright
- Copyright © 2015 by Pleiades Publishing, Ltd.
- Subject
- Chemistry; Physical Chemistry; Inorganic Chemistry
- ISSN
- 1070-3284
- eISSN
- 1608-3318
- DOI
- 10.1134/S1070328415090031
- Publisher site
- See Article on Publisher Site
Abstract
The results of studying the reaction behavior of tungsten hexachloride toward organic iso(thio)cyanates and their combinations with nitriles are generalized. The factors determining the multiplet insertion of iso(thio)cyanates at the W–Cl bond and the conditions of symmetrical or asymmetrical crosslinking of the inserted fragments into heterocycles upon their trimerization (on the basis of the X-ray structural data on the products of the partial or complete hydrolysis of the complexes) are discussed. The reasons determining the direction of the combined insertion of heterocumulenes and nitriles at the W–Cl or W–N bond are considered, which is important for the targeted design of complexes of various architecture and new poorly accessible related heterocyclic compounds.
Journal
Russian Journal of Coordination Chemistry – Springer Journals
Published: Sep 2, 2015