Regeneration of a spent iron-molybdenum catalyst for partial oxidation of methanol to formaldehyde was studied. A stage-by-stage dissolution of molybdenum and iron oxides in solutions of ammonia and weak nitric acid, respectively, is suggested. A dependence of the catalyst composition on the pH of the medium and temperature and its effect on the catalyst properties in the reaction of methanol oxidation to formaldehyde was revealed.
Russian Journal of Applied Chemistry – Springer Journals
Published: Jul 14, 2015
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